Selective synthesis of four- and five-membered metallaheterocycles via CC bond-forming reactions of η²-iminoacyl and η³-1-azaallyl complexes of tungsten with alkyl isocyanides

Keyphrases

• Acid-catalyzed Reaction 33%
• Alkyl Isocyanides 100%
• Amino 33%
• Aminocarbene 66%
• Aminopyrrole 33%
• Azaallyl 100%
• Bond Length 33%
• Bond-forming Reactions 100%
• Carbon Bond 66%
• Efficient Procedure 33%
• Electron Delocalization 33%
• Five-membered 100%
• Four-legged 33%
• H-D Exchange 33%
• Imino 33%
• Isocyanide 33%
• Isocyanide Insertion 33%
• Metallaheterocycle 100%
• Piano-stool Complexes 33%
• Selective Synthesis 100%
• Single Crystal X-ray Diffraction Study 33%
• Solid-state Structures 33%
• Spectroscopic Data 33%
• Structural Information 33%
• Tungsten 100%
• Vinyl 33%

Chemistry

• Bond Length 33%
• Catalysis 33%
• Electron Delocalization 33%
• Hydrogen 33%
• Isocyanide 100%
• Single Crystal X-Ray Diffraction 33%
• Structure 33%