Selective metal-to-ring alkyl migration during irradiation of CpFe(CO)2[CHPh(OSiMe3)]

Nancy E. Carpenter, Masood A. Khan, Kenneth M. Nicholas

    Research output: Contribution to journalArticlepeer-review

    6 Scopus citations

    Abstract

    UV-vis irradiation of CpFe(CO)2[CHPh-(OSiMe3)] (1b) in the presence of PPh3 produces η4-{exo-C5H5[CHPh(OSiMe 3]}Fe(CO)2PPh3 (3b), the product of alkyl migration from iron to the Cp ring, in good yield.

    Original languageEnglish (US)
    Pages (from-to)1569-1570
    Number of pages2
    JournalOrganometallics
    Volume18
    Issue number8
    DOIs
    StatePublished - Apr 12 1999

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