Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites

Patricia Cheung; Aditya Bhan; Glenn J. Sunley; Enrique Iglesia

doi:10.1002/anie.200503898

Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites

Patricia Cheung, Aditya Bhan, Glenn J. Sunley, Enrique Iglesia

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

382 Scopus citations

Abstract

(Chemical Equation Presented) A simpler way: Acidic zeolites catalyze dimethyl ether carbonylation to methyl acetate at low temperatures with high selectivity and catalyst stability. This approach provides a halide-free heterogeneous catalytic route to acetic acid and methyl acetate.

Original language	English (US)
Pages (from-to)	1617-1620
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	10
DOIs	https://doi.org/10.1002/anie.200503898
State	Published - Feb 27 2006

Keywords

Carbonylation
Carboxylic acids
Ethers
Heterogeneous catalysis
Zeolites

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10.1002/anie.200503898

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title = "Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites",

abstract = "(Chemical Equation Presented) A simpler way: Acidic zeolites catalyze dimethyl ether carbonylation to methyl acetate at low temperatures with high selectivity and catalyst stability. This approach provides a halide-free heterogeneous catalytic route to acetic acid and methyl acetate.",

keywords = "Carbonylation, Carboxylic acids, Ethers, Heterogeneous catalysis, Zeolites",

author = "Patricia Cheung and Aditya Bhan and Sunley, \{Glenn J.\} and Enrique Iglesia",

year = "2006",

month = feb,

day = "27",

doi = "10.1002/anie.200503898",

language = "English (US)",

volume = "45",

pages = "1617--1620",

journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley and Sons Ltd",

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TY - JOUR

T1 - Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites

AU - Cheung, Patricia

AU - Bhan, Aditya

AU - Sunley, Glenn J.

AU - Iglesia, Enrique

PY - 2006/2/27

Y1 - 2006/2/27

N2 - (Chemical Equation Presented) A simpler way: Acidic zeolites catalyze dimethyl ether carbonylation to methyl acetate at low temperatures with high selectivity and catalyst stability. This approach provides a halide-free heterogeneous catalytic route to acetic acid and methyl acetate.

AB - (Chemical Equation Presented) A simpler way: Acidic zeolites catalyze dimethyl ether carbonylation to methyl acetate at low temperatures with high selectivity and catalyst stability. This approach provides a halide-free heterogeneous catalytic route to acetic acid and methyl acetate.

KW - Carbonylation

KW - Carboxylic acids

KW - Ethers

KW - Heterogeneous catalysis

KW - Zeolites

UR - https://www.scopus.com/pages/publications/33746309713

UR - https://www.scopus.com/inward/citedby.url?scp=33746309713&partnerID=8YFLogxK

U2 - 10.1002/anie.200503898

DO - 10.1002/anie.200503898

M3 - Article

C2 - 16444792

AN - SCOPUS:33746309713

SN - 1433-7851

VL - 45

SP - 1617

EP - 1620

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 10

ER -

Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites

Abstract

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