Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites

Patricia Cheung; Aditya Bhan; Glenn J. Sunley; Enrique Iglesia

doi:10.1002/anie.200503898

Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites

Patricia Cheung, Aditya Bhan, Glenn J. Sunley, Enrique Iglesia

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

359 Scopus citations

Abstract

(Chemical Equation Presented) A simpler way: Acidic zeolites catalyze dimethyl ether carbonylation to methyl acetate at low temperatures with high selectivity and catalyst stability. This approach provides a halide-free heterogeneous catalytic route to acetic acid and methyl acetate.

Original language	English (US)
Pages (from-to)	1617-1620
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	10
DOIs	https://doi.org/10.1002/anie.200503898
State	Published - Feb 27 2006

Keywords

Carbonylation
Carboxylic acids
Ethers
Heterogeneous catalysis
Zeolites

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10.1002/anie.200503898

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title = "Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites",

abstract = "(Chemical Equation Presented) A simpler way: Acidic zeolites catalyze dimethyl ether carbonylation to methyl acetate at low temperatures with high selectivity and catalyst stability. This approach provides a halide-free heterogeneous catalytic route to acetic acid and methyl acetate.",

keywords = "Carbonylation, Carboxylic acids, Ethers, Heterogeneous catalysis, Zeolites",

author = "Patricia Cheung and Aditya Bhan and Sunley, {Glenn J.} and Enrique Iglesia",

year = "2006",

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day = "27",

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journal = "Angewandte Chemie - International Edition",

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T1 - Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites

AU - Cheung, Patricia

AU - Bhan, Aditya

AU - Sunley, Glenn J.

AU - Iglesia, Enrique

PY - 2006/2/27

Y1 - 2006/2/27

N2 - (Chemical Equation Presented) A simpler way: Acidic zeolites catalyze dimethyl ether carbonylation to methyl acetate at low temperatures with high selectivity and catalyst stability. This approach provides a halide-free heterogeneous catalytic route to acetic acid and methyl acetate.

AB - (Chemical Equation Presented) A simpler way: Acidic zeolites catalyze dimethyl ether carbonylation to methyl acetate at low temperatures with high selectivity and catalyst stability. This approach provides a halide-free heterogeneous catalytic route to acetic acid and methyl acetate.

KW - Carbonylation

KW - Carboxylic acids

KW - Ethers

KW - Heterogeneous catalysis

KW - Zeolites

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M3 - Article

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AN - SCOPUS:33746309713

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

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ER -

Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites

Abstract

Keywords

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