Abstract
A simple, one-pot, and high-yielding synthesis of 1,3-diphenyldisiloxane is presented. The preparation of similar symmetrical disiloxane materials is also accomplished with this same protocol. This mechano-chemical procedure is efficient and highly scalable, furnishing a convenient route to hydrido-disiloxanes from widely accessible commercially available silanes.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 278-281 |
| Number of pages | 4 |
| Journal | Synthesis (Germany) |
| Volume | 50 |
| Issue number | 2 |
| DOIs | |
| State | Published - Jan 18 2018 |
Bibliographical note
Funding Information:This work was supported by the University of Minnesota College of Pharmacy, an NSF Graduate Research Fellowship to J.A.B. (GRFP: 00039202), a Bighley Fellowship to J.A.B. (UMN-COP), and a Chemical-Biology Interface Training Grant to C.G.E. (T32-GM008700).
Publisher Copyright:
© Georg Thieme Verlag KG Stuttgart New York.
Keywords
- ball-milling
- chlorination
- copper
- one-pot
- silane
- siloxane
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