Scalable Synthesis of Hydrido-Disiloxanes from Silanes: A One-Pot Preparation of 1,3-Diphenyldisiloxane from Phenylsilane

Joseph A. Buonomo, Carter G. Eiden, Courtney C. Aldrich

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A simple, one-pot, and high-yielding synthesis of 1,3-diphenyldisiloxane is presented. The preparation of similar symmetrical disiloxane materials is also accomplished with this same protocol. This mechano-chemical procedure is efficient and highly scalable, furnishing a convenient route to hydrido-disiloxanes from widely accessible commercially available silanes.

Original languageEnglish (US)
Pages (from-to)278-281
Number of pages4
JournalSynthesis (Germany)
Volume50
Issue number2
DOIs
StatePublished - Jan 18 2018

Bibliographical note

Funding Information:
This work was supported by the University of Minnesota College of Pharmacy, an NSF Graduate Research Fellowship to J.A.B. (GRFP: 00039202), a Bighley Fellowship to J.A.B. (UMN-COP), and a Chemical-Biology Interface Training Grant to C.G.E. (T32-GM008700).

Publisher Copyright:
© Georg Thieme Verlag KG Stuttgart New York.

Keywords

  • ball-milling
  • chlorination
  • copper
  • one-pot
  • silane
  • siloxane

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