Ruthenium-mediated oxidation under buffered conditions: A simple and useful protocol for the synthesis of norbornyl α-diketones with acid sensitive functionalities

Faiz Ahmed Khan; Ch Sudheer

doi:10.1002/adsc.200900042

Ruthenium-mediated oxidation under buffered conditions: A simple and useful protocol for the synthesis of norbornyl α-diketones with acid sensitive functionalities

Faiz Ahmed Khan
, Ch Sudheer

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The supported ruthenium-catalyzed oxidation of the 1,2-dihaloalkene moiety in tetrahalo-norbornyl derivatives possessing acid labile functionalities to afford the corresponding α-diketones is demonstrated. The protocol was successfully applied in the synthesis of a cyclopenta-annulated δ-lactone derived from D-mannitol. &

Original language	English (US)
Pages (from-to)	939-944
Number of pages	6
Journal	Advanced Synthesis and Catalysis
Volume	351
Issue number	6
DOIs	https://doi.org/10.1002/adsc.200900042
State	Published - Apr 2009
Externally published	Yes

Keywords

Diels-Alder reaction
Oxidation
Ruthenium
Supported catalysts
α-diketones
δ-lactones

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10.1002/adsc.200900042

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abstract = "The supported ruthenium-catalyzed oxidation of the 1,2-dihaloalkene moiety in tetrahalo-norbornyl derivatives possessing acid labile functionalities to afford the corresponding α-diketones is demonstrated. The protocol was successfully applied in the synthesis of a cyclopenta-annulated δ-lactone derived from D-mannitol. \&",

keywords = "Diels-Alder reaction, Oxidation, Ruthenium, Supported catalysts, α-diketones, δ-lactones",

author = "Khan, \{Faiz Ahmed\} and Ch Sudheer",

year = "2009",

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doi = "10.1002/adsc.200900042",

language = "English (US)",

volume = "351",

pages = "939--944",

journal = "Advanced Synthesis and Catalysis",

issn = "1615-4150",

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T2 - A simple and useful protocol for the synthesis of norbornyl α-diketones with acid sensitive functionalities

AU - Khan, Faiz Ahmed

AU - Sudheer, Ch

PY - 2009/4

Y1 - 2009/4

N2 - The supported ruthenium-catalyzed oxidation of the 1,2-dihaloalkene moiety in tetrahalo-norbornyl derivatives possessing acid labile functionalities to afford the corresponding α-diketones is demonstrated. The protocol was successfully applied in the synthesis of a cyclopenta-annulated δ-lactone derived from D-mannitol. &

AB - The supported ruthenium-catalyzed oxidation of the 1,2-dihaloalkene moiety in tetrahalo-norbornyl derivatives possessing acid labile functionalities to afford the corresponding α-diketones is demonstrated. The protocol was successfully applied in the synthesis of a cyclopenta-annulated δ-lactone derived from D-mannitol. &

KW - Diels-Alder reaction

KW - Oxidation

KW - Ruthenium

KW - Supported catalysts

KW - α-diketones

KW - δ-lactones

UR - https://www.scopus.com/pages/publications/65249088577

UR - https://www.scopus.com/pages/publications/65249088577#tab=citedBy

U2 - 10.1002/adsc.200900042

DO - 10.1002/adsc.200900042

M3 - Article

AN - SCOPUS:65249088577

SN - 1615-4150

VL - 351

SP - 939

EP - 944

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 6

ER -

Ruthenium-mediated oxidation under buffered conditions: A simple and useful protocol for the synthesis of norbornyl α-diketones with acid sensitive functionalities

Abstract

Keywords

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