Abstract
The supported ruthenium-catalyzed oxidation of the 1,2-dihaloalkene moiety in tetrahalo-norbornyl derivatives possessing acid labile functionalities to afford the corresponding α-diketones is demonstrated. The protocol was successfully applied in the synthesis of a cyclopenta-annulated δ-lactone derived from D-mannitol. &
Original language | English (US) |
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Pages (from-to) | 939-944 |
Number of pages | 6 |
Journal | Advanced Synthesis and Catalysis |
Volume | 351 |
Issue number | 6 |
DOIs | |
State | Published - Apr 2009 |
Externally published | Yes |
Keywords
- Diels-Alder reaction
- Oxidation
- Ruthenium
- Supported catalysts
- α-diketones
- δ-lactones