Ruthenium-mediated oxidation under buffered conditions: A simple and useful protocol for the synthesis of norbornyl α-diketones with acid sensitive functionalities

Faiz Ahmed Khan, Ch Sudheer

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

The supported ruthenium-catalyzed oxidation of the 1,2-dihaloalkene moiety in tetrahalo-norbornyl derivatives possessing acid labile functionalities to afford the corresponding α-diketones is demonstrated. The protocol was successfully applied in the synthesis of a cyclopenta-annulated δ-lactone derived from D-mannitol. &

Original languageEnglish (US)
Pages (from-to)939-944
Number of pages6
JournalAdvanced Synthesis and Catalysis
Volume351
Issue number6
DOIs
StatePublished - Apr 2009
Externally publishedYes

Keywords

  • Diels-Alder reaction
  • Oxidation
  • Ruthenium
  • Supported catalysts
  • α-diketones
  • δ-lactones

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