Room temperature acylketene formation 1,3-dioxin-4-ones via silver(I) activation of phenylthioacetoacetate in the presence of ketones

Aaron E. May; Thomas R. Hoye

doi:10.1021/jo101372v

Room temperature acylketene formation 1,3-dioxin-4-ones via silver(I) activation of phenylthioacetoacetate in the presence of ketones

Aaron E. May, Thomas R. Hoye

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

Silver(I) activation of thioacetoacetates in the presence of ketones produces 1,3-dioxin-4-ones. Mechanistic studies addressing the intermediacy of an acylketene intermediate are described.

Original language	English (US)
Pages (from-to)	6054-6056
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	75
Issue number	17
DOIs	https://doi.org/10.1021/jo101372v
State	Published - Sep 3 2010

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title = "Room temperature acylketene formation 1,3-dioxin-4-ones via silver(I) activation of phenylthioacetoacetate in the presence of ketones",

abstract = "Silver(I) activation of thioacetoacetates in the presence of ketones produces 1,3-dioxin-4-ones. Mechanistic studies addressing the intermediacy of an acylketene intermediate are described.",

author = "May, {Aaron E.} and Hoye, {Thomas R.}",

year = "2010",

month = sep,

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doi = "10.1021/jo101372v",

language = "English (US)",

volume = "75",

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journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "17",

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T1 - Room temperature acylketene formation 1,3-dioxin-4-ones via silver(I) activation of phenylthioacetoacetate in the presence of ketones

AU - May, Aaron E.

AU - Hoye, Thomas R.

PY - 2010/9/3

Y1 - 2010/9/3

N2 - Silver(I) activation of thioacetoacetates in the presence of ketones produces 1,3-dioxin-4-ones. Mechanistic studies addressing the intermediacy of an acylketene intermediate are described.

AB - Silver(I) activation of thioacetoacetates in the presence of ketones produces 1,3-dioxin-4-ones. Mechanistic studies addressing the intermediacy of an acylketene intermediate are described.

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U2 - 10.1021/jo101372v

DO - 10.1021/jo101372v

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JF - Journal of Organic Chemistry

IS - 17

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Room temperature acylketene formation 1,3-dioxin-4-ones via silver(I) activation of phenylthioacetoacetate in the presence of ketones

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