Room temperature acylketene formation 1,3-dioxin-4-ones via silver(I) activation of phenylthioacetoacetate in the presence of ketones

Aaron E. May, Thomas R. Hoye

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

Silver(I) activation of thioacetoacetates in the presence of ketones produces 1,3-dioxin-4-ones. Mechanistic studies addressing the intermediacy of an acylketene intermediate are described.

Original languageEnglish (US)
Pages (from-to)6054-6056
Number of pages3
JournalJournal of Organic Chemistry
Volume75
Issue number17
DOIs
StatePublished - Sep 3 2010

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