Ring scission of diastereomeric 4-butylspiropentylcarbinyl radicals as a chemical model for identifying enzyme-catalyzed FAD adducts resulting from spiropentylacetyl-CoA

Keyphrases

• Enzyme Catalysis 100%
• Ring Opening 100%
• Bromide 100%
• Scission 100%
• Chemical Model 100%
• C(V) 100%
• Alcohol 50%
• Fatty Acid Metabolism 50%
• Isomerization 50%
• Butyl 50%
• C1-C2 50%
• Estimated Rates 50%
• Stereochemical Assignment 50%
• NOE Experiments 50%
• High-level Ab Initio Calculations 50%
• Seven Steps 50%
• Bond Cleavage 50%
• Hydride Reduction 50%
• C2 Symmetry 50%
• Butyltins 50%
• 1-Heptyne 50%

Chemistry

• Diastereomer 100%
• Ring Opening Reaction 100%
• Isomerization 50%
• Nuclear Overhauser Effect 50%
• Ab Initio Calculation 50%
• Fatty Acids 50%