Ring expansion of a 2-rhodaoxetane: Insertion chemistry with unsaturated molecules

Addison N. Desnoyer; Alexander Dauth; Brian O. Patrick; Jennifer A. Love

doi:10.1039/c3dt52569d

Ring expansion of a 2-rhodaoxetane: Insertion chemistry with unsaturated molecules

Addison N. Desnoyer, Alexander Dauth, Brian O. Patrick, Jennifer A. Love

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

A 2-rhodaoxetane was found to react with unsaturated electrophiles, such as highly electron-deficient acetylene dicarboxylates, CS₂ and various aldehydes, to form a series of six-membered metallacycles. These metallacycles were characterized by ¹H, ¹³C and 2D NMR spectroscopic techniques, as well as HRMS and, for one complex, XRD. In some cases, the insertions were found to be reversible.

Original language	English (US)
Pages (from-to)	30-33
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	1
DOIs	https://doi.org/10.1039/c3dt52569d
State	Published - Jan 7 2014

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10.1039/c3dt52569d

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abstract = "A 2-rhodaoxetane was found to react with unsaturated electrophiles, such as highly electron-deficient acetylene dicarboxylates, CS2 and various aldehydes, to form a series of six-membered metallacycles. These metallacycles were characterized by 1H, 13C and 2D NMR spectroscopic techniques, as well as HRMS and, for one complex, XRD. In some cases, the insertions were found to be reversible.",

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T2 - Insertion chemistry with unsaturated molecules

AU - Desnoyer, Addison N.

AU - Dauth, Alexander

AU - Patrick, Brian O.

AU - Love, Jennifer A.

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Y1 - 2014/1/7

N2 - A 2-rhodaoxetane was found to react with unsaturated electrophiles, such as highly electron-deficient acetylene dicarboxylates, CS2 and various aldehydes, to form a series of six-membered metallacycles. These metallacycles were characterized by 1H, 13C and 2D NMR spectroscopic techniques, as well as HRMS and, for one complex, XRD. In some cases, the insertions were found to be reversible.

AB - A 2-rhodaoxetane was found to react with unsaturated electrophiles, such as highly electron-deficient acetylene dicarboxylates, CS2 and various aldehydes, to form a series of six-membered metallacycles. These metallacycles were characterized by 1H, 13C and 2D NMR spectroscopic techniques, as well as HRMS and, for one complex, XRD. In some cases, the insertions were found to be reversible.

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Ring expansion of a 2-rhodaoxetane: Insertion chemistry with unsaturated molecules

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