Reversible, Stepwise Addition of 1,2-Diester-Substituted Alkenes to Ru2[(CH3)2PCH2P(CH3)2]2(CO)5. Crystal and Molecular Structure of the Diruthenacyclobutane Complex Ru2[(CH3)2PCH2P(CH3)2]2(CO)4[μ-η1:η1-C2(H)2(CO2CH3)2]•C7H8

Kimberly A. Johnson; Wayne L. Gladfelter

doi:10.1021/om00048a004

Reversible, Stepwise Addition of 1,2-Diester-Substituted Alkenes to Ru₂[(CH₃)₂PCH₂P(CH₃)₂]₂(CO)₅. Crystal and Molecular Structure of the Diruthenacyclobutane Complex Ru₂[(CH₃)₂PCH₂P(CH₃)₂]₂(CO)₄[μ-η¹:η¹-C₂(H)₂(CO₂CH₃)₂]•C₇H₈

Kimberly A. Johnson, Wayne L. Gladfelter

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

cis- and trans-Diester-substituted alkenes react with Ru₂(dmpm)₂(CO)₅ (dmpm = bis(dimethyl-phosphino)methane) to form the trans-substituted diruthenacyclobutane. This process was shown to be stepwise and reversible, and a zwitterionic intermediate is proposed.

Original language	English (US)
Pages (from-to)	376-378
Number of pages	3
Journal	Organometallics
Volume	10
Issue number	2
DOIs	https://doi.org/10.1021/om00048a004
State	Published - Feb 1 1991

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10.1021/om00048a004

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Reversible, Stepwise Addition of 1,2-Diester-Substituted Alkenes to Ru₂[(CH₃)₂PCH₂P(CH₃)₂]₂(CO)₅. Crystal and Molecular Structure of the Diruthenacyclobutane Complex Ru₂[(CH₃)₂PCH₂P(CH₃)₂]₂(CO)₄[μ-η¹:η¹-C₂(H)₂(CO₂CH₃)₂]•C₇H₈. / Johnson, Kimberly A.; Gladfelter, Wayne L.
In: Organometallics, Vol. 10, No. 2, 01.02.1991, p. 376-378.

Research output: Contribution to journal › Article › peer-review

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