Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups

Chulsung Bae; John F. Hartwig; Hoyong Chung; Nicole K. Harris; Karen A. Switek; Marc A. Hillmyer

doi:10.1002/anie.200501837

Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups

Chulsung Bae, John F. Hartwig, Hoyong Chung, Nicole K. Harris, Karen A. Switek, Marc A. Hillmyer

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

(Chemical Equation Presented) The tail end: The Rh-catalyzed selective functionalization of commercial linear low-density polyethylene (LLDPE) with boron reagents is demonstrated. Subsequent oxidation and transformations of the boron-containing polymer yields materials that contain a variety of polar functionalities, such as hydroxy, amino, and formyl groups, at the termini of the side chains (see scheme).

Original language	English (US)
Pages (from-to)	6410-6413
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	39
DOIs	https://doi.org/10.1002/anie.200501837
State	Published - Oct 7 2005

Keywords

Boron
C-H activation
Homogeneous catalysis
Polymers
Rhodium

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10.1002/anie.200501837

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abstract = "(Chemical Equation Presented) The tail end: The Rh-catalyzed selective functionalization of commercial linear low-density polyethylene (LLDPE) with boron reagents is demonstrated. Subsequent oxidation and transformations of the boron-containing polymer yields materials that contain a variety of polar functionalities, such as hydroxy, amino, and formyl groups, at the termini of the side chains (see scheme).",

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AU - Bae, Chulsung

AU - Hartwig, John F.

AU - Chung, Hoyong

AU - Harris, Nicole K.

AU - Switek, Karen A.

AU - Hillmyer, Marc A.

PY - 2005/10/7

Y1 - 2005/10/7

N2 - (Chemical Equation Presented) The tail end: The Rh-catalyzed selective functionalization of commercial linear low-density polyethylene (LLDPE) with boron reagents is demonstrated. Subsequent oxidation and transformations of the boron-containing polymer yields materials that contain a variety of polar functionalities, such as hydroxy, amino, and formyl groups, at the termini of the side chains (see scheme).

AB - (Chemical Equation Presented) The tail end: The Rh-catalyzed selective functionalization of commercial linear low-density polyethylene (LLDPE) with boron reagents is demonstrated. Subsequent oxidation and transformations of the boron-containing polymer yields materials that contain a variety of polar functionalities, such as hydroxy, amino, and formyl groups, at the termini of the side chains (see scheme).

KW - Boron

KW - C-H activation

KW - Homogeneous catalysis

KW - Polymers

KW - Rhodium

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 39

ER -

Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups

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Keywords

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