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Abstract
This work aimed to decrease the water permeability (PH2O) while simultaneously maintaining low oxygen permeability (PO2) in ethylene vinyl alcohol (EVOH)-based copolymers by introducing high levels of backbone regioregularity and stereoregularity. Both regioregular atactic and isotactic EVOH samples with 75 mol % ethylene were prepared by a ring-opening metathesis polymerization (ROMP)-hydrogenation-deprotection approach and then compared to commercial EVOH(44) (containing 44 mol % ethylene) as a low PO2 standard with poor water barrier characteristics (i.e., high PH2O). The high levels of regioregularity and stereoregularity in these copolymers increased the melting temperature (Tm), degree of crystallinity (χc), and glass-transition temperature (Tg) compared to less regular structures. EVOH(44) demonstrated the highest Tm but lower χc and Tg values as compared to that of the isotactic polymer. Wide-angle X-ray scattering showed that semicrystalline EVOH(44) exhibited a monoclinic structure characteristic of commercial materials, while ROMP-derived polymers displayed an intermediate structure between monoclinic and orthorhombic. Tensile testing showed that isotacticity resulted in brittle mechanical behavior, while the atactic and commercial EVOH(44) samples had higher tensile toughness values. Although EVOH(44) had the lowest PO2 of the samples explored, the atactic and tough ROMP-derived polymer approached this value of PO2 while having a PH2O over 3 times lower than that of commercial EVOH(44).
Original language | English (US) |
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Pages (from-to) | 208-213 |
Number of pages | 6 |
Journal | ACS Polymers Au |
Volume | 4 |
Issue number | 3 |
DOIs | |
State | Published - Jun 12 2024 |
Bibliographical note
Publisher Copyright:© 2024 The Authors. Published by American Chemical Society.
Keywords
- functional polyolefins
- gas barrier materials
- metathesis
- packaging
- semicrystalline
MRSEC Support
- Shared
PubMed: MeSH publication types
- Journal Article
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