TY - JOUR
T1 - Reductive Disproportionation of NO Mediated by Copper Complexes
T2 - Modeling N2O Generation by Copper Proteins and Heterogeneous Catalysts
AU - Ruggiero, Christy E.
AU - Carrier, Susan M.
AU - Tolman, William B
PY - 1994/5/2
Y1 - 1994/5/2
N2 - Nitrito‐O,O‐copper complexes and dinitrogen oxide are the products of the reaction of excess NO with the nitrosyl complexes [LCu(NO)] (L = substituted tris(pyrazolyl)hydroborate), a process that models environmentally important transformations carried out by copper ions in proteins and zeolites. According to the results of kinetic studies, the involvement of dimeric copper species in the rate‐determining step is ruled out, which suggests that NO coupling occurs at a single metal ion.
AB - Nitrito‐O,O‐copper complexes and dinitrogen oxide are the products of the reaction of excess NO with the nitrosyl complexes [LCu(NO)] (L = substituted tris(pyrazolyl)hydroborate), a process that models environmentally important transformations carried out by copper ions in proteins and zeolites. According to the results of kinetic studies, the involvement of dimeric copper species in the rate‐determining step is ruled out, which suggests that NO coupling occurs at a single metal ion.
UR - http://www.scopus.com/inward/record.url?scp=0027950819&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0027950819&partnerID=8YFLogxK
U2 - 10.1002/anie.199408951
DO - 10.1002/anie.199408951
M3 - Article
AN - SCOPUS:0027950819
SN - 0570-0833
VL - 33
SP - 895
EP - 897
JO - Angewandte Chemie International Edition in English
JF - Angewandte Chemie International Edition in English
IS - 8
ER -