Record-Low and Anisotropic Thermal Conductivity of a Quasi-One-Dimensional Bulk ZrTe 5 Single Crystal

Jie Zhu, Tianli Feng, Scott Mills, Peipei Wang, Xuewang Wu, Liyuan Zhang, Sokrates T. Pantelides, Xu Du, Xiaojia Wang

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Zirconium pentatelluride (ZrTe 5 ) has recently attracted renewed interest owing to many of its newly discovered extraordinary physical properties, such as 2D and 3D topological-insulator behavior, pressure-induced superconductivity, Weyl semimetal behavior, Zeeman splitting, and resistivity anomaly. The quasi-one-dimensional structure of single-crystal ZrTe 5 also promises large anisotropy in its thermal properties, which have not yet been studied. In this work, via time-domain thermoreflectance measurements, ZrTe 5 single crystals are discovered to possess a record-low thermal conductivity along the b-axis (through-plane), as small as 0.33 ± 0.03 W m -1 K -1 at room temperature. This ultralow b-axis thermal conductivity is 12 times smaller than its a-axis thermal conductivity (4 ± 1 W m -1 K -1 ) owing to the material's asymmetrical crystalline structure. First-principles calculations are further conducted to reveal the physical origins of the ultralow b-axis thermal conductivity, which can be attributed to: (1) the resonant bonding and strong lattice anharmonicity induced by electron lone pairs, (2) the weak interlayer van der Waals interactions, and (3) the heavy mass of Te atoms, which results in low phonon group velocity. This work sheds light on the design and engineering of high-efficiency thermal insulators for applications such as thermal barrier coatings, thermoelectrics, thermal energy storage, and thermal management.

Original languageEnglish (US)
Pages (from-to)40740-40747
Number of pages8
JournalACS Applied Materials and Interfaces
Volume10
Issue number47
DOIs
StatePublished - Nov 28 2018

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Thermal conductivity
Single crystals
Storage management
Metalloids
Thermal barrier coatings
Superconductivity
Thermal energy
Zirconium
Temperature control
Energy storage
Anisotropy
Thermodynamic properties
Physical properties
Crystalline materials
Atoms
Electrons
Temperature

Keywords

  • anisotropic thermal transport
  • first-principles calculation
  • quasi-one-dimensional material
  • time-domain thermoreflectance
  • ultralow thermal conductivity

How much support was provided by MRSEC?

  • Partial

Reporting period for MRSEC

  • Period 5

PubMed: MeSH publication types

  • Journal Article

Cite this

Record-Low and Anisotropic Thermal Conductivity of a Quasi-One-Dimensional Bulk ZrTe 5 Single Crystal . / Zhu, Jie; Feng, Tianli; Mills, Scott; Wang, Peipei; Wu, Xuewang; Zhang, Liyuan; Pantelides, Sokrates T.; Du, Xu; Wang, Xiaojia.

In: ACS Applied Materials and Interfaces, Vol. 10, No. 47, 28.11.2018, p. 40740-40747.

Research output: Contribution to journalArticle

Zhu, Jie ; Feng, Tianli ; Mills, Scott ; Wang, Peipei ; Wu, Xuewang ; Zhang, Liyuan ; Pantelides, Sokrates T. ; Du, Xu ; Wang, Xiaojia. / Record-Low and Anisotropic Thermal Conductivity of a Quasi-One-Dimensional Bulk ZrTe 5 Single Crystal In: ACS Applied Materials and Interfaces. 2018 ; Vol. 10, No. 47. pp. 40740-40747.
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