TY - JOUR
T1 - Recent advances in well-defined, late transition metal complexes that make and/or break C-N, C-O and C-S bonds
AU - Desnoyer, Addison N.
AU - Love, Jennifer A.
N1 - Publisher Copyright:
© 2017 The Royal Society of Chemistry.
PY - 2017/1
Y1 - 2017/1
N2 - Chemical transformations that result in either the formation or cleavage of carbon-heteroatom bonds are among the most important processes in the chemical sciences. Herein, we present a review on the reactivity of well-defined, late-transition metal complexes that result in the making and breaking of C-N, C-O and C-S bonds via fundamental organometallic reactions, i.e. oxidative addition, reductive elimination, insertion and elimination reactions. When appropriate, emphasis is placed on structural and spectroscopic characterization techniques, as well as mechanistic data.
AB - Chemical transformations that result in either the formation or cleavage of carbon-heteroatom bonds are among the most important processes in the chemical sciences. Herein, we present a review on the reactivity of well-defined, late-transition metal complexes that result in the making and breaking of C-N, C-O and C-S bonds via fundamental organometallic reactions, i.e. oxidative addition, reductive elimination, insertion and elimination reactions. When appropriate, emphasis is placed on structural and spectroscopic characterization techniques, as well as mechanistic data.
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U2 - 10.1039/c6cs00150e
DO - 10.1039/c6cs00150e
M3 - Review article
C2 - 27849097
AN - SCOPUS:85008698738
SN - 0306-0012
VL - 46
SP - 197
EP - 238
JO - Chemical Society Reviews
JF - Chemical Society Reviews
IS - 1
ER -