Rearrangement of the trans-tricyclo[4.2.0.01,3]oct-4-enyl skeleton

Elena S. Koltun, Steven R. Kass

Research output: Contribution to journalArticle

2 Scopus citations

Abstract

The acetolysis of a tosylate with a novel tricyclic skeleton was examined. Two major products (a tosylate and an acetate) are formed and both are the result of a skeletal rearrangement. A mechanism to account for the observed products is proposed and preliminary kinetic data are reported. (C) 2000 Elsevier Science Ltd.

Original languageEnglish (US)
Pages (from-to)2591-2594
Number of pages4
JournalTetrahedron
Volume56
Issue number17
DOIs
StatePublished - Apr 21 2000

Keywords

  • Kinetics
  • Rearrangements
  • Solvolysis
  • Tricyclo[4.2.0.0]oct-4-enyl skeleton

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