Rearrangement of the trans-tricyclo[4.2.0.01,3]oct-4-enyl skeleton

Elena S. Koltun; Steven R. Kass

doi:10.1016/S0040-4020(00)00199-X

Rearrangement of the trans-tricyclo[4.2.0.0^1,3]oct-4-enyl skeleton

Elena S. Koltun, Steven R. Kass

Chemistry (Twin Cities)

Research output: Contribution to journal › Article

2 Scopus citations

Abstract

The acetolysis of a tosylate with a novel tricyclic skeleton was examined. Two major products (a tosylate and an acetate) are formed and both are the result of a skeletal rearrangement. A mechanism to account for the observed products is proposed and preliminary kinetic data are reported. (C) 2000 Elsevier Science Ltd.

Original language	English (US)
Pages (from-to)	2591-2594
Number of pages	4
Journal	Tetrahedron
Volume	56
Issue number	17
DOIs	https://doi.org/10.1016/S0040-4020(00)00199-X
State	Published - Apr 21 2000

Keywords

Kinetics
Rearrangements
Solvolysis
Tricyclo[4.2.0.0]oct-4-enyl skeleton

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10.1016/S0040-4020(00)00199-X

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Koltun, E. S., & Kass, S. R. (2000). Rearrangement of the trans-tricyclo[4.2.0.0^1,3]oct-4-enyl skeleton. Tetrahedron, 56(17), 2591-2594. https://doi.org/10.1016/S0040-4020(00)00199-X

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AU - Kass, Steven R.

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N2 - The acetolysis of a tosylate with a novel tricyclic skeleton was examined. Two major products (a tosylate and an acetate) are formed and both are the result of a skeletal rearrangement. A mechanism to account for the observed products is proposed and preliminary kinetic data are reported. (C) 2000 Elsevier Science Ltd.

AB - The acetolysis of a tosylate with a novel tricyclic skeleton was examined. Two major products (a tosylate and an acetate) are formed and both are the result of a skeletal rearrangement. A mechanism to account for the observed products is proposed and preliminary kinetic data are reported. (C) 2000 Elsevier Science Ltd.

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KW - Solvolysis

KW - Tricyclo[4.2.0.0]oct-4-enyl skeleton

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