TY - JOUR
T1 - Reaktionen von elektronenreichen heterocyclen mit orthocarbonsäure‐derivaten. I. Zum reaktionsverhalten von acyclischen orthoestern mit indolen unter säurekatalyse
AU - Akgün, E.
AU - Pindur, U.
AU - Müller, J.
PY - 1983
Y1 - 1983
N2 - By kinetic controlled reaction of alkoxycarbenium‐ions 1a‐1d, generated in the medium, with the indoles 2a‐2c the methanes 3, 4 or the ketones 5 and 6 are the single products. In the reaction with 1d the minimum of reactivity is achieved. The experimental condition of the reactions allow an estimation of the reactivity of 1a‐1d and 2a‐2c.
AB - By kinetic controlled reaction of alkoxycarbenium‐ions 1a‐1d, generated in the medium, with the indoles 2a‐2c the methanes 3, 4 or the ketones 5 and 6 are the single products. In the reaction with 1d the minimum of reactivity is achieved. The experimental condition of the reactions allow an estimation of the reactivity of 1a‐1d and 2a‐2c.
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U2 - 10.1002/jhet.5570200530
DO - 10.1002/jhet.5570200530
M3 - Article
AN - SCOPUS:84986492861
SN - 0022-152X
VL - 20
SP - 1303
EP - 1305
JO - Journal of Heterocyclic Chemistry
JF - Journal of Heterocyclic Chemistry
IS - 5
ER -