Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: Structural characterization of Claisen condensation adduct

Gabriela A. Grasa; Rohit Singh; Natalie M. Scott; Edwin D. Stevens; Steven P. Nolan

doi:10.1039/b410986d

Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: Structural characterization of Claisen condensation adduct

Gabriela A. Grasa, Rohit Singh, Natalie M. Scott, Edwin D. Stevens, Steven P. Nolan

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Abstract

The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C-H bond activation. The structure of the product has been established by a single crystal diffraction study.

Original language	English (US)
Pages (from-to)	2890-2891
Number of pages	2
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/b410986d
State	Published - Dec 21 2004
Externally published	Yes

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10.1039/b410986d

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title = "Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: Structural characterization of Claisen condensation adduct",

abstract = "The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C-H bond activation. The structure of the product has been established by a single crystal diffraction study.",

author = "Grasa, {Gabriela A.} and Rohit Singh and Scott, {Natalie M.} and Stevens, {Edwin D.} and Nolan, {Steven P.}",

year = "2004",

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doi = "10.1039/b410986d",

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pages = "2890--2891",

journal = "Chemical Communications",

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T1 - Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid

T2 - Structural characterization of Claisen condensation adduct

AU - Grasa, Gabriela A.

AU - Singh, Rohit

AU - Scott, Natalie M.

AU - Stevens, Edwin D.

AU - Nolan, Steven P.

PY - 2004/12/21

Y1 - 2004/12/21

N2 - The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C-H bond activation. The structure of the product has been established by a single crystal diffraction study.

AB - The reactivity of a N-heterocyclic carbene (NHC) with a pseudo-acid (ester in this case) is described. The product results from an unusual C-H bond activation. The structure of the product has been established by a single crystal diffraction study.

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Reactivity of a N-heterocyclic carbene, 1,3-di-(1-adamantyl) imidazol-2-ylidene, with a pseudo-acid: Structural characterization of Claisen condensation adduct

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