Reactivity of a 1:1 copper-oxygen complex: Isolation of a Cu(II)-o-iminosemiquinonato species

Anne M. Reynolds; Elizabeth A. Lewis; Nermeen W. Aboelella; William B Tolman

doi:10.1039/b418939f

Reactivity of a 1:1 copper-oxygen complex: Isolation of a Cu(II)-o-iminosemiquinonato species

Anne M. Reynolds
, Elizabeth A. Lewis
, Nermeen W. Aboelella
, William B Tolman

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

While a 1:1 Cu-O₂ adduct is generally unreactive with organic substrates, phosphines displace O₂ via an associative process and added Cu(I) leads to a novel internal ligand oxidation to yield a Cu(II)-o-iminosemiquinone complex.

Original language	English (US)
Pages (from-to)	2014-2016
Number of pages	3
Journal	Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/b418939f
State	Published - Apr 21 2005

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10.1039/b418939f

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title = "Reactivity of a 1:1 copper-oxygen complex: Isolation of a Cu(II)-o-iminosemiquinonato species",

abstract = "While a 1:1 Cu-O2 adduct is generally unreactive with organic substrates, phosphines displace O2 via an associative process and added Cu(I) leads to a novel internal ligand oxidation to yield a Cu(II)-o-iminosemiquinone complex.",

author = "Reynolds, \{Anne M.\} and Lewis, \{Elizabeth A.\} and Aboelella, \{Nermeen W.\} and Tolman, \{William B\}",

year = "2005",

month = apr,

day = "21",

doi = "10.1039/b418939f",

language = "English (US)",

pages = "2014--2016",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - Reactivity of a 1:1 copper-oxygen complex

T2 - Isolation of a Cu(II)-o-iminosemiquinonato species

AU - Reynolds, Anne M.

AU - Lewis, Elizabeth A.

AU - Aboelella, Nermeen W.

AU - Tolman, William B

PY - 2005/4/21

Y1 - 2005/4/21

N2 - While a 1:1 Cu-O2 adduct is generally unreactive with organic substrates, phosphines displace O2 via an associative process and added Cu(I) leads to a novel internal ligand oxidation to yield a Cu(II)-o-iminosemiquinone complex.

AB - While a 1:1 Cu-O2 adduct is generally unreactive with organic substrates, phosphines displace O2 via an associative process and added Cu(I) leads to a novel internal ligand oxidation to yield a Cu(II)-o-iminosemiquinone complex.

UR - https://www.scopus.com/pages/publications/18044375807

UR - https://www.scopus.com/pages/publications/18044375807#tab=citedBy

U2 - 10.1039/b418939f

DO - 10.1039/b418939f

M3 - Article

C2 - 15834490

AN - SCOPUS:18044375807

SN - 1359-7345

SP - 2014

EP - 2016

JO - Chemical Communications

JF - Chemical Communications

IS - 15

ER -

Reactivity of a 1:1 copper-oxygen complex: Isolation of a Cu(II)-o-iminosemiquinonato species

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