Reactions of laser-ablated iron atoms with N2O, NO, and O2 in condensing nitrogen. Infrared spectra and density functional calculations of ternary iron nitride oxide molecules

Lester Andrews, George V. Chertihin, Angelo Citra, Matthew Neurock

Research output: Contribution to journalArticle

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Abstract

Reactions of laser-ablated Fe atoms with N2O, NO, and O2 in excess N2 during condensation at 10 K produced new absorptions with 15N and 18O shifts that are assigned to the new ternary iron nitride oxide molecules NFeO, NFeO2, and N2FeO. DFT calculations of structure and isotopic frequencies support these assignments.

Original languageEnglish (US)
Pages (from-to)11235-11241
Number of pages7
JournalJournal of physical chemistry
Volume100
Issue number27
DOIs
StatePublished - Jul 4 1996

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