TY - JOUR
T1 - Reactionof 1,1′-Bis(diphenylphosphino)ferrocene with Mercuric Halides, Mercuric Cyanide, and Other Lewis Acids
AU - Mann, Kent R.
AU - Morrison, William H.
AU - Hendrickson, David N.
PY - 1974/5/1
Y1 - 1974/5/1
N2 - The reaction of 1,1′-Fe(cpPPh2)2with HgX2(X = Cl, Br, I, SCN) gives Fe(cpPPh2)2·nHgX2(n = 1,2). Infrared, electronic absorption, polarographic, and 57Fe Mossbauer spectroscopic data are presented to show that in every case it is the phosphorus not the iron atom that is bonded to the mercury. The reaction of 1,1′-Fe(cpPPh2)2with Hg(CN)2in the presence of acid gives [(Fe(cpPPh2)2)2Hg](X)2(X-= BF4-, PF6-) where physical data show that the dication has a P-Hg interaction. Ruthenocene reacts with SnX4(X = Cl, Br) to give compounds with Ru-Sn bonds. The products of the reaction of 1,1′-Fe-(cpPPh2)2and SnX4are described.
AB - The reaction of 1,1′-Fe(cpPPh2)2with HgX2(X = Cl, Br, I, SCN) gives Fe(cpPPh2)2·nHgX2(n = 1,2). Infrared, electronic absorption, polarographic, and 57Fe Mossbauer spectroscopic data are presented to show that in every case it is the phosphorus not the iron atom that is bonded to the mercury. The reaction of 1,1′-Fe(cpPPh2)2with Hg(CN)2in the presence of acid gives [(Fe(cpPPh2)2)2Hg](X)2(X-= BF4-, PF6-) where physical data show that the dication has a P-Hg interaction. Ruthenocene reacts with SnX4(X = Cl, Br) to give compounds with Ru-Sn bonds. The products of the reaction of 1,1′-Fe-(cpPPh2)2and SnX4are described.
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U2 - 10.1021/ic50135a033
DO - 10.1021/ic50135a033
M3 - Article
AN - SCOPUS:0141979170
SN - 0020-1669
VL - 13
SP - 1180
EP - 1185
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 5
ER -