Reaction of lithium alkynolates with acid chlorides: A conventional approach to the preparation of ynol esters

Viktor V. Zhdankin; Peter J. Stang

doi:10.1016/S0040-4039(00)60318-0

Reaction of lithium alkynolates with acid chlorides: A conventional approach to the preparation of ynol esters

Viktor V. Zhdankin, Peter J. Stang

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

Lithium alkynolates (R-CCOLi, R = CH₃, n- C₄H₉, t-C₄H₉, Ph), generated in situ from dibromomethylketones and a strong base, react with electrophiles (diethyl chlorophosphate or benzoyl chloride) with the formation of the corresponding ynol esters.

Original language	English (US)
Pages (from-to)	1461-1462
Number of pages	2
Journal	Tetrahedron Letters
Volume	34
Issue number	9
DOIs	https://doi.org/10.1016/S0040-4039(00)60318-0
State	Published - Feb 26 1993

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title = "Reaction of lithium alkynolates with acid chlorides: A conventional approach to the preparation of ynol esters",

abstract = "Lithium alkynolates (R-CCOLi, R = CH3, n- C4H9, t-C4H9, Ph), generated in situ from dibromomethylketones and a strong base, react with electrophiles (diethyl chlorophosphate or benzoyl chloride) with the formation of the corresponding ynol esters.",

author = "Zhdankin, {Viktor V.} and Stang, {Peter J.}",

year = "1993",

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doi = "10.1016/S0040-4039(00)60318-0",

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journal = "Tetrahedron Letters",

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T1 - Reaction of lithium alkynolates with acid chlorides

T2 - A conventional approach to the preparation of ynol esters

AU - Zhdankin, Viktor V.

AU - Stang, Peter J.

PY - 1993/2/26

Y1 - 1993/2/26

N2 - Lithium alkynolates (R-CCOLi, R = CH3, n- C4H9, t-C4H9, Ph), generated in situ from dibromomethylketones and a strong base, react with electrophiles (diethyl chlorophosphate or benzoyl chloride) with the formation of the corresponding ynol esters.

AB - Lithium alkynolates (R-CCOLi, R = CH3, n- C4H9, t-C4H9, Ph), generated in situ from dibromomethylketones and a strong base, react with electrophiles (diethyl chlorophosphate or benzoyl chloride) with the formation of the corresponding ynol esters.

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ER -

Reaction of lithium alkynolates with acid chlorides: A conventional approach to the preparation of ynol esters

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