Abstract
We report a series of calculations designed to show the efficiency of adiabatic basis sets for V-V energy transfer in diatom-diatom collisions. We do find that these basis sets are very efficient for both symmetric and nonsymmetric cases. For resonant V-V energy transfer at low energies we obtain quantitative accuracy with a two-state model. The only dynamical calculations required for this model are two phase shifts.
Original language | English (US) |
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Pages (from-to) | 5287-5294 |
Number of pages | 8 |
Journal | The Journal of chemical physics |
Volume | 76 |
Issue number | 11 |
DOIs | |
State | Published - 1981 |