Raman imaging of surface and sub-surface graphene oxide in fiber reinforced polymer nanocomposites

Amber McCreary, Qi An, Aaron M. Forster, Kunwei Liu, Siyao He, Christopher W. Macosko, Andreas Stein, Angela R. Hight Walker

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

Visualization of dispersion is a challenging and unresolved issue for high aspect ratio nanofillers, such as surface-modified graphene oxide (mGO) and carbon nanotubes, in fiber reinforced polymer (FRP) composites. Conventional metrologies to study dispersion (location, spacing, size, etc.) have proven difficult and impractical when the fibers are present, particularly at the industrially-relevant, low mass fractions of nanofillers. Here, Raman spectroscopy and imaging are exploited to investigate the dispersion of mGO in unsaturated polyester (UP) resin composites both with and without glass microfiber reinforcement. Through comparative TEM and Raman maps on the same sample area, we validate a detailed Raman methodology to detect mGO agglomerate positions, even at low loadings of < 0.1 % by mass, where the sensitivity of the mGO Raman signal is dependent on incident laser wavelength. More importantly, we expand this to FRP composites, where by a proper choice of incident wavelength to avoid glass fiber fluorescence, Raman imaging is able to identify surface (2D) and sub-surface (3D) mGO microstructures near microfibers in the inter- and intralaminar regions. This measurement technique will find significant use in the FRP composite community as a readily available method to qualitatively correlate dispersion properties to processing techniques and/or mechanical performance.

Original languageEnglish (US)
Pages (from-to)793-801
Number of pages9
JournalCarbon
Volume143
DOIs
StatePublished - Mar 2019

Bibliographical note

Funding Information:
A.M. and A.R.H.W. would like to acknowledge the National Institute of Standards and Technology (NIST) / National Research Council Postdoctoral Research Associateship Program and NIST-STRS (Scientific and Technical Research and Services) for funding. A.M.F. and Q.A. would like to acknowledge Bharath Natarajan (NIST) for help with microtome processing of polymer nanocomposites. The synthesis of the mGO samples was funded by Adama Materials.

Publisher Copyright:
© 2018

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