Quantitative determination of siliceous species in sodium silicate solutions by 29Si n.m.r. spectroscopy

A. V. McCormick; A. T. Bell; C. J. Radke

doi:10.1016/0144-2449(87)90048-0

Quantitative determination of siliceous species in sodium silicate solutions by ²⁹Si n.m.r. spectroscopy

A. V. McCormick, A. T. Bell, C. J. Radke

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

50 Scopus citations

Abstract

Quantitative ²⁹Si FT n.m.r. spectra of sodium silicate solutions are used to characterize the distribution of soluble silicate species as the solution composition is changed. The silicate ratios and concentrations used are those of interest in the study of compositional influence on zeolite synthesis [1-3 mol% SiO₂; SiO₂ Na₂O = 1-3]. The concentration of each species depends strongly on the silicate ratio and can be maximized by selection of that ratio. Over the range studied, dependence of the species distribution on silicate concentration is considerably less dramatic. Comparisons are made with the limited previous data.

Original language	English (US)
Pages (from-to)	183-190
Number of pages	8
Journal	Zeolites
Volume	7
Issue number	3
DOIs	https://doi.org/10.1016/0144-2449(87)90048-0
State	Published - May 1987

Bibliographical note

Funding Information:
This work was supported by the Office of Basic Energy Sciences, Material Sciences Division of the US Department of Energy under Contract DE-AC03-76SF00098. Fellowship support for Alon V. McCormick was provided by the National Science Foundation.

Keywords

N.m.r.
sodium silicate solutions
synthesis

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10.1016/0144-2449(87)90048-0

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title = "Quantitative determination of siliceous species in sodium silicate solutions by 29Si n.m.r. spectroscopy",

abstract = "Quantitative 29Si FT n.m.r. spectra of sodium silicate solutions are used to characterize the distribution of soluble silicate species as the solution composition is changed. The silicate ratios and concentrations used are those of interest in the study of compositional influence on zeolite synthesis [1-3 mol% SiO2; SiO2 Na2O = 1-3]. The concentration of each species depends strongly on the silicate ratio and can be maximized by selection of that ratio. Over the range studied, dependence of the species distribution on silicate concentration is considerably less dramatic. Comparisons are made with the limited previous data.",

keywords = "N.m.r., sodium silicate solutions, synthesis",

author = "McCormick, {A. V.} and Bell, {A. T.} and Radke, {C. J.}",

note = "Funding Information: This work was supported by the Office of Basic Energy Sciences, Material Sciences Division of the US Department of Energy under Contract DE-AC03-76SF00098. Fellowship support for Alon V. McCormick was provided by the National Science Foundation.",

year = "1987",

month = may,

doi = "10.1016/0144-2449(87)90048-0",

language = "English (US)",

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T1 - Quantitative determination of siliceous species in sodium silicate solutions by 29Si n.m.r. spectroscopy

AU - McCormick, A. V.

AU - Bell, A. T.

AU - Radke, C. J.

N1 - Funding Information: This work was supported by the Office of Basic Energy Sciences, Material Sciences Division of the US Department of Energy under Contract DE-AC03-76SF00098. Fellowship support for Alon V. McCormick was provided by the National Science Foundation.

PY - 1987/5

Y1 - 1987/5

N2 - Quantitative 29Si FT n.m.r. spectra of sodium silicate solutions are used to characterize the distribution of soluble silicate species as the solution composition is changed. The silicate ratios and concentrations used are those of interest in the study of compositional influence on zeolite synthesis [1-3 mol% SiO2; SiO2 Na2O = 1-3]. The concentration of each species depends strongly on the silicate ratio and can be maximized by selection of that ratio. Over the range studied, dependence of the species distribution on silicate concentration is considerably less dramatic. Comparisons are made with the limited previous data.

AB - Quantitative 29Si FT n.m.r. spectra of sodium silicate solutions are used to characterize the distribution of soluble silicate species as the solution composition is changed. The silicate ratios and concentrations used are those of interest in the study of compositional influence on zeolite synthesis [1-3 mol% SiO2; SiO2 Na2O = 1-3]. The concentration of each species depends strongly on the silicate ratio and can be maximized by selection of that ratio. Over the range studied, dependence of the species distribution on silicate concentration is considerably less dramatic. Comparisons are made with the limited previous data.

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