Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

Casey J. Stephenson; Joseph T. Hupp; Omar K. Farha

doi:10.1039/c5qi00010f

Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

Casey J. Stephenson
, Joseph T. Hupp
, Omar K. Farha

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.

Original language	English (US)
Pages (from-to)	448-452
Number of pages	5
Journal	Inorganic Chemistry Frontiers
Volume	2
Issue number	5
DOIs	https://doi.org/10.1039/c5qi00010f
State	Published - May 2015

Bibliographical note

Publisher Copyright:
This journal is © the Partner Organisations 2015.

Publisher link

10.1039/c5qi00010f

Find It

Find It at U of M Libraries

Cite this

@article{a32b820f3fed43bea328a8b09f91fd70,

title = "Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes",

abstract = "Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.",

author = "Stephenson, \{Casey J.\} and Hupp, \{Joseph T.\} and Farha, \{Omar K.\}",

note = "Publisher Copyright: This journal is {\textcopyright} the Partner Organisations 2015.",

year = "2015",

month = may,

doi = "10.1039/c5qi00010f",

language = "English (US)",

volume = "2",

pages = "448--452",

journal = "Inorganic Chemistry Frontiers",

issn = "2052-1545",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

AU - Stephenson, Casey J.

AU - Hupp, Joseph T.

AU - Farha, Omar K.

N1 - Publisher Copyright: This journal is © the Partner Organisations 2015.

PY - 2015/5

Y1 - 2015/5

N2 - Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.

AB - Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.

UR - https://www.scopus.com/pages/publications/84934953863

UR - https://www.scopus.com/pages/publications/84934953863#tab=citedBy

U2 - 10.1039/c5qi00010f

DO - 10.1039/c5qi00010f

M3 - Article

AN - SCOPUS:84934953863

SN - 2052-1545

VL - 2

SP - 448

EP - 452

JO - Inorganic Chemistry Frontiers

JF - Inorganic Chemistry Frontiers

IS - 5

ER -

Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

Abstract

Bibliographical note

Publisher link

Find It

Other files and links

Fingerprint

Cite this