TY - JOUR
T1 - Propane aromatization over HZSM-5 and Ga/HZSM-5 catalysts
AU - Bhan, Aditya
AU - Delgass, W. Nicholas
PY - 2008/3
Y1 - 2008/3
N2 - The selective transformation of light alkanes to aromatics that are more valuable and versatile feedstocks for the chemical industry is one of the major challenges of catalytic chemistry. The complexity of the aromatization chemistry makes it difficult to unravel reaction mechanisms and, mechanistic information is largely developed from observed product distributions. This article reviews the current mechanistic understanding for the conversion of propane to aromatic compounds over HZSM-5 and Ga/HZSM-5 catalysts based on experimental as well as theoretical studies. Following a general discussion of acidity and confinement effects in these systems, this review focuses on understanding specific reactions occurring on Brønsted acid sites in HZSM-5. Mechanistic details available from Density Functional Theory (DFT) calculations, as well as kinetic modeling efforts for various complex hydrocarbon systems are critically reviewed. A detailed, tabulated review of the literature compares the catalytic performance of gallium modified ZSM-5 catalysts and subsequently the promotional effect of gallium as an additive is critically discussed in terms of the nature of the active sites, as well as the new reaction pathways introduced by gallium addition.
AB - The selective transformation of light alkanes to aromatics that are more valuable and versatile feedstocks for the chemical industry is one of the major challenges of catalytic chemistry. The complexity of the aromatization chemistry makes it difficult to unravel reaction mechanisms and, mechanistic information is largely developed from observed product distributions. This article reviews the current mechanistic understanding for the conversion of propane to aromatic compounds over HZSM-5 and Ga/HZSM-5 catalysts based on experimental as well as theoretical studies. Following a general discussion of acidity and confinement effects in these systems, this review focuses on understanding specific reactions occurring on Brønsted acid sites in HZSM-5. Mechanistic details available from Density Functional Theory (DFT) calculations, as well as kinetic modeling efforts for various complex hydrocarbon systems are critically reviewed. A detailed, tabulated review of the literature compares the catalytic performance of gallium modified ZSM-5 catalysts and subsequently the promotional effect of gallium as an additive is critically discussed in terms of the nature of the active sites, as well as the new reaction pathways introduced by gallium addition.
KW - Alkane activation
KW - Aromatization
KW - Computational catalysis
KW - Hydrocarbon reactions on zeolites
KW - Kinetic modeling
UR - http://www.scopus.com/inward/record.url?scp=38949215510&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=38949215510&partnerID=8YFLogxK
U2 - 10.1080/01614940701804745
DO - 10.1080/01614940701804745
M3 - Review article
AN - SCOPUS:38949215510
SN - 0161-4940
VL - 50
SP - 19
EP - 151
JO - Catalysis Reviews - Science and Engineering
JF - Catalysis Reviews - Science and Engineering
IS - 1
ER -