Abstract
Iridium trisboryl complexes containing bisphosphine and bipyridine ligands and pinacolate and catecholate substituents on boron are reported. A large difference in reactivity towards the borylation of C-H bonds is observed for this series of trisboryl complexes, and this difference is attributed to the electron-donating properties of the pinacolate vs. catecholate groups, and the steric and electronic properties of bipyridine vs. bisphosphine ligands.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 5603-5605 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Issue number | 37 |
| DOIs | |
| State | Published - 2009 |
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