Production of bio-oil and biochar from soapstock via microwave-assisted co-catalytic fast pyrolysis

Leilei Dai, Liangliang Fan, Yuhuan Liu, Roger Ruan, Yunpu Wang, Yue Zhou, Yunfeng Zhao, Zhenting Yu

Research output: Contribution to journalArticle

35 Scopus citations

Abstract

In this study, production of bio-oil and biochar from soapstock via microwave-assisted co-catalytic fast pyrolysis combining the advantages of in-situ and ex-situ catalysis was performed. The effects of catalyst and pyrolysis temperature on product fractional yields and bio-oil chemical compositions were investigated. From the perspective of bio-oil yield, the optimal pyrolysis temperature was 550 °C. The use of catalysts reduced the water content, and the addition of bentonite increased the bio-oil yield. Up to 84.16 wt.% selectivity of hydrocarbons in the bio-oil was obtained in the co-catalytic process. In addition, the co-catalytic process can reduce the proportion of oxygenates in the bio-oil to 15.84 wt.% and eliminate the N-containing compounds completely. The addition of bentonite enhanced the BET surface area of bio-char. In addition, the bio-char removal efficiency of Cd2+ from soapstock pyrolysis in presence of bentonite was 27.4 wt.% higher than without bentonite.

Original languageEnglish (US)
Pages (from-to)1-8
Number of pages8
JournalBioresource Technology
Volume225
DOIs
StatePublished - Feb 1 2017

Keywords

  • Bentonite
  • Bio-char
  • Bio-oil
  • Catalytic fast pyrolysis
  • HZSM-5
  • Microwave

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