Pressure and Temperature Induced Dual Responsive Molecular Crystals: Effect of Polymorphism

Ragaverthini Chinnasamy, Bhushan Munjal, Raj Suryanarayanan, Abdul Malik P. Peedikakkal, Manish Kumar Mishra, Soumyajit Ghosh

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The rapid conversion of energy into mechanical motion is a crucial requirement in the design of advanced flexible sensors and optoelectronic devices. Responsive materials that show mechanical movement when exposed to different external stimuli such as heat, pressure, humidity, or light can serve as technomimetics in smart actuator and microrobotic devices. However, it is quite challenging to design molecular crystals which can respond to two or more external stimuli. Herein, we report dimorphic forms (1a and 1b) of 2-hydroxy-3,5-dibromobenzylidine-4-fluoro-3-nitroaniline (Crystal 1) where form 1a is brittle and form 1b is elastically bendable. Both polymorphs exhibit progressive thermosalient responses which are seemingly different in nature. One polymorph (1a) shows jumping, while the other (1b) shows bending. The property difference is solely attributed to the inherent crystal packing and linked to the differences in the molecular conformations, structural packing, and intermolecular interactions. 2-Hydroxy-3-bromo-5-chlorobenzylidine-4-fluoro-3-nitroaniline (Crystal 2) was nonthermosalient but was mechanically flexible. Variable temperature powder X-ray diffractometry revealed anisotropic crystallographic face expansion-a possible explanation for the different thermosalient behaviors of the dimorphs.

Original languageEnglish (US)
Pages (from-to)615-624
Number of pages10
JournalCrystal Growth and Design
Volume22
Issue number1
DOIs
StatePublished - Jan 5 2022

Bibliographical note

Funding Information:
R.C. thanks SRMIST for research fellowship. S.G. thanks DST-SERB for Core Research Grant (File No: CRG/2020/000885). M.K.M. thanks VIT for providing VIT SEED GRANT for this research work. R.S. thanks the William and Mildred Peters endowment fund. B.M. and R.S. acknowledge the Characterization Facility, University of Minnesota, which receives partial support from NSF through the MRSEC program.

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