Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

Akira Yoshimura; Khiem C. Nguyen; Scott C. Klasen; Akio Saito; Victor N. Nemykin; Viktor V. Zhdankin

doi:10.1039/c5cc02009c

Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

Akira Yoshimura
, Khiem C. Nguyen
, Scott C. Klasen
, Akio Saito
, Victor N. Nemykin
, Viktor V. Zhdankin

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

67 Scopus citations

Abstract

A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant.

Original language	English (US)
Pages (from-to)	7835-7838
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	37
DOIs	https://doi.org/10.1039/c5cc02009c
State	Published - May 7 2015

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© The Royal Society of Chemistry 2015.

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abstract = "A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant.",

author = "Akira Yoshimura and Nguyen, \{Khiem C.\} and Klasen, \{Scott C.\} and Akio Saito and Nemykin, \{Victor N.\} and Zhdankin, \{Viktor V.\}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2015.",

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month = may,

day = "7",

doi = "10.1039/c5cc02009c",

language = "English (US)",

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T1 - Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

AU - Yoshimura, Akira

AU - Nguyen, Khiem C.

AU - Klasen, Scott C.

AU - Saito, Akio

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor V.

PY - 2015/5/7

Y1 - 2015/5/7

N2 - A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant.

AB - A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant.

UR - https://www.scopus.com/pages/publications/84928659917

UR - https://www.scopus.com/pages/publications/84928659917#tab=citedBy

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DO - 10.1039/c5cc02009c

M3 - Article

AN - SCOPUS:84928659917

SN - 1359-7345

VL - 51

SP - 7835

EP - 7838

JO - Chemical Communications

JF - Chemical Communications

IS - 37

ER -

Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

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