Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

Akira Yoshimura; Khiem C. Nguyen; Scott C. Klasen; Akio Saito; Victor N. Nemykin; Viktor V. Zhdankin

doi:10.1039/c5cc02009c

Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

Akira Yoshimura, Khiem C. Nguyen, Scott C. Klasen, Akio Saito, Victor N. Nemykin, Viktor V. Zhdankin

Chemistry & Biochemistry

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60 Scopus citations

Abstract

A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant. This journal is

Original language	English (US)
Pages (from-to)	7835-7838
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	37
DOIs	https://doi.org/10.1039/c5cc02009c
State	Published - May 7 2015

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© The Royal Society of Chemistry 2015.

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abstract = "A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant. This journal is",

author = "Akira Yoshimura and Nguyen, {Khiem C.} and Klasen, {Scott C.} and Akio Saito and Nemykin, {Victor N.} and Zhdankin, {Viktor V.}",

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doi = "10.1039/c5cc02009c",

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T1 - Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

AU - Yoshimura, Akira

AU - Nguyen, Khiem C.

AU - Klasen, Scott C.

AU - Saito, Akio

AU - Nemykin, Victor N.

AU - Zhdankin, Viktor V.

PY - 2015/5/7

Y1 - 2015/5/7

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AB - A new pseudocyclic triflate derivative of benziodoxole (IBA-OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA-OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant. This journal is

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JO - Chemical Communications

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Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

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