Preparation, structure, and chemistry of phosphorane-derived phenyliodonium sulfonates

Viktor Zhdankin, Olena Maydanovych, Jon Herschbach, Jessica Bruno, Elena D. Matveeva, Nikolai S. Zefirov

Research output: Contribution to journalArticle

25 Scopus citations

Abstract

New triphenylphosphorane-derived phenyliodonium triflates and tosylates were prepared by the reaction of the appropriate iodosobenzene sulfonate with stabilized phosphonium ylides. Structure of the triflate derivative was determined by a single-crystal X-ray analysis. These compounds represent a potentially useful class of reagents that combine in one molecule synthetic advantages of a phosphonium ylide and an iodonium salt.

Original languageEnglish (US)
Pages (from-to)2359-2361
Number of pages3
JournalTetrahedron Letters
Volume43
Issue number13
DOIs
StatePublished - Mar 25 2002

Keywords

  • Hypervalent iodine
  • Iodonium
  • Phosphonium
  • X-ray crystallography

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    Zhdankin, V., Maydanovych, O., Herschbach, J., Bruno, J., Matveeva, E. D., & Zefirov, N. S. (2002). Preparation, structure, and chemistry of phosphorane-derived phenyliodonium sulfonates. Tetrahedron Letters, 43(13), 2359-2361. https://doi.org/10.1016/S0040-4039(02)00275-7