Preparation of WO3 network squares for ultrasensitive photodetectors

Qianning Yi, Chenguo Hu, Rusen Yang, Hong Liu, Buyong Wan, Yan Zhang

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20 Scopus citations


Three-dimensional WO3 network squares have been fabricated on a large scale by a hydrothermal method at 160 °C without any template or surfactant. The characterization of the network squares with X-ray diffraction, scanning electron microscopy, and transmission electron microscopy indicates a single crystalline hexagonal structure with a square of side length up to 20 μm. The influence of pH value on the morphology of the final product has been studied, indicating that more uniform WO3 network squares can be obtained at pH 1.7. A possible growth mechanism involves the Ostwald ripening, oriented attachment and etching effect. The UV-vis reflection spectrum indicates a band gap of ∼3.2 eV. The photodetector based on a single WO3 network square shows remarkable photosensitivity under intermittent illumination of the simulated sunlight, which could mainly be attributed to the specific network structure of WO3 and the Schottky contacts.

Original languageEnglish (US)
Pages (from-to)L255-L261
JournalJournal of Alloys and Compounds
Issue number26
StatePublished - Jun 30 2011

Bibliographical note

Funding Information:
This work has been funded by the NSFC (60976055), NSFDYS : 50925205, the Fundamental Research Funds for the Central Universities (CDJXS10102208) and the large-scale equipment sharing fund of Chongqing University .


  • Chemical synthesis
  • Light absorption and reflection
  • Nanostructured materials
  • Photoconductivity


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