Preparation of [18O]‐chlorocarbonylsulfenyl chloride

Andrew W. Mott, Steven J. Eastep, Urszula Słomczynska, George Barany

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Abstract

[18O]‐Chlorocarbonylsulfenyl chloride with an isotopic purity of 92% was prepared in three steps starting with the [18O]‐hydrolysis of 2‐ethyl‐1,3‐dioxolane to [18O]‐propanal, which was then converted to [18O]‐O‐1‐methylpropyl S‐methyl dithiocarbonate, which was then chlorinated to give the title compound. Distilled yields for the three steps were 57%, 49%, and 40% respectively.

Original languageEnglish (US)
Pages (from-to)329-336
Number of pages8
JournalJournal of Labelled Compounds and Radiopharmaceuticals
Volume21
Issue number4
DOIs
StatePublished - Apr 1984

Keywords

  • [O]‐chlorocarbonylsulfenyl chloride
  • [O]‐propanal
  • [O]‐xanthate

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