Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) 3·SO3: Stable and water-soluble analog of iodosylbenzene

Alexey Y. Koposov; Brian C. Netzel; Mekhman S. Yusubov; Victor N. Nemykin; Alexander Y. Nazarenko; Viktor Zhdankin

doi:10.1002/ejoc.200700625

Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) ₃·SO₃: Stable and water-soluble analog of iodosylbenzene

Alexey Y. Koposov, Brian C. Netzel, Mekhman S. Yusubov, Victor N. Nemykin, Alexander Y. Nazarenko, Viktor Zhdankin

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

36 Scopus citations

Abstract

New phenyliodine(III) sulfate (PhIO)₃·SO₃, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.

Original language	English (US)
Pages (from-to)	4475-4478
Number of pages	4
Journal	European Journal of Organic Chemistry
Issue number	27
DOIs	https://doi.org/10.1002/ejoc.200700625
State	Published - 2007

Keywords

Hypervalent compounds
Iodine
Iodosylbenzene
Oxidation
X-ray diffraction

Publisher link

10.1002/ejoc.200700625

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title = "Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) 3·SO3: Stable and water-soluble analog of iodosylbenzene",

abstract = "New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.",

keywords = "Hypervalent compounds, Iodine, Iodosylbenzene, Oxidation, X-ray diffraction",

author = "Koposov, {Alexey Y.} and Netzel, {Brian C.} and Yusubov, {Mekhman S.} and Nemykin, {Victor N.} and Nazarenko, {Alexander Y.} and Viktor Zhdankin",

year = "2007",

doi = "10.1002/ejoc.200700625",

language = "English (US)",

pages = "4475--4478",

journal = "European Journal of Organic Chemistry",

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T1 - Preparation and structure of oligomeric iodosylbenzene sulfate (PhIO) 3·SO3

T2 - Stable and water-soluble analog of iodosylbenzene

AU - Koposov, Alexey Y.

AU - Netzel, Brian C.

AU - Yusubov, Mekhman S.

AU - Nemykin, Victor N.

AU - Nazarenko, Alexander Y.

AU - Zhdankin, Viktor

PY - 2007

Y1 - 2007

N2 - New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.

AB - New phenyliodine(III) sulfate (PhIO)3·SO3, which has a complex polymeric structure of the trimeric iodosylbenzene units linked by sulfate anions, can be conveniently prepared by treatment of (diacetoxy)iodobenzene with sodium bisulfate in the presence of water. This sulfate can find practical application as a readily available, stable, and water-soluble hypervalent iodine reagent with a reactivity pattern similar to that of iodosylbenzene.

KW - Hypervalent compounds

KW - Iodine

KW - Iodosylbenzene

KW - Oxidation

KW - X-ray diffraction

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