Preparation and reactivity of polystyrene-supported iodosylbenzene: Convenient recyclable oxidizing reagent and catalyst

Jiang Min Chen; Xiao Mei Zeng; Kyle Middleton; Mekhman S. Yusubov; Viktor Zhdankin

doi:10.1055/s-0030-1260788

Preparation and reactivity of polystyrene-supported iodosylbenzene: Convenient recyclable oxidizing reagent and catalyst

Jiang Min Chen, Xiao Mei Zeng, Kyle Middleton, Mekhman S. Yusubov, Viktor Zhdankin

Chemistry & Biochemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A facile preparation of novel polystyrene-supported iodosylbenzene (PS-ISB, loading of IO up to 1.50 mmol/g) from iodopolystyrene is described. This resin has been successfully used for efficient oxidation of a diverse collection of alcohols to aldehydes and ketones in the presence of BF₃OEt ₂. PS-ISB can also be employed as efficient co-catalyst in combination with RuCl₃ in the catalytic oxidation of alcohols and aromatic hydrocarbons, respectively, to corresponding carboxylic acids and ketones using Oxone as the stoichiometric oxidant.

Original language	English (US)
Pages (from-to)	1613-1617
Number of pages	5
Journal	Synlett
Issue number	11
DOIs	https://doi.org/10.1055/s-0030-1260788
State	Published - Jun 17 2011

Keywords

iodine
iodosylbenzene
oxidation
polymers
recyclable reagent

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10.1055/s-0030-1260788

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title = "Preparation and reactivity of polystyrene-supported iodosylbenzene: Convenient recyclable oxidizing reagent and catalyst",

abstract = "A facile preparation of novel polystyrene-supported iodosylbenzene (PS-ISB, loading of IO up to 1.50 mmol/g) from iodopolystyrene is described. This resin has been successfully used for efficient oxidation of a diverse collection of alcohols to aldehydes and ketones in the presence of BF3OEt 2. PS-ISB can also be employed as efficient co-catalyst in combination with RuCl3 in the catalytic oxidation of alcohols and aromatic hydrocarbons, respectively, to corresponding carboxylic acids and ketones using Oxone as the stoichiometric oxidant.",

keywords = "iodine, iodosylbenzene, oxidation, polymers, recyclable reagent",

author = "Chen, {Jiang Min} and Zeng, {Xiao Mei} and Kyle Middleton and Yusubov, {Mekhman S.} and Viktor Zhdankin",

year = "2011",

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doi = "10.1055/s-0030-1260788",

language = "English (US)",

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T1 - Preparation and reactivity of polystyrene-supported iodosylbenzene

T2 - Convenient recyclable oxidizing reagent and catalyst

AU - Chen, Jiang Min

AU - Zeng, Xiao Mei

AU - Middleton, Kyle

AU - Yusubov, Mekhman S.

AU - Zhdankin, Viktor

PY - 2011/6/17

Y1 - 2011/6/17

N2 - A facile preparation of novel polystyrene-supported iodosylbenzene (PS-ISB, loading of IO up to 1.50 mmol/g) from iodopolystyrene is described. This resin has been successfully used for efficient oxidation of a diverse collection of alcohols to aldehydes and ketones in the presence of BF3OEt 2. PS-ISB can also be employed as efficient co-catalyst in combination with RuCl3 in the catalytic oxidation of alcohols and aromatic hydrocarbons, respectively, to corresponding carboxylic acids and ketones using Oxone as the stoichiometric oxidant.

AB - A facile preparation of novel polystyrene-supported iodosylbenzene (PS-ISB, loading of IO up to 1.50 mmol/g) from iodopolystyrene is described. This resin has been successfully used for efficient oxidation of a diverse collection of alcohols to aldehydes and ketones in the presence of BF3OEt 2. PS-ISB can also be employed as efficient co-catalyst in combination with RuCl3 in the catalytic oxidation of alcohols and aromatic hydrocarbons, respectively, to corresponding carboxylic acids and ketones using Oxone as the stoichiometric oxidant.

KW - iodine

KW - iodosylbenzene

KW - oxidation

KW - polymers

KW - recyclable reagent

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ER -

Preparation and reactivity of polystyrene-supported iodosylbenzene: Convenient recyclable oxidizing reagent and catalyst

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