Preparation and Reactivity of Mononuclear (η 5 -Cyclopentadienyl)cobalt Carbene Complexes

David W. Macomber, Robin D. Rogers

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

5 -C 5 H s )Co(CO) 2 reacts with bis(1,3-dimethylimidazolin-2-ylidene) to furnish the first mononuclear cyclopentadienylcobalt carbene complex 1. Complex 1 reacts with several electrophilic reagents including Ph 2 S 2 to produce the structurally characterized paramagnetic cyclopentadienylcobalt carbene complex 4.

Original languageEnglish (US)
Pages (from-to)1485-1487
Number of pages3
JournalOrganometallics
Volume4
Issue number8
DOIs
StatePublished - Jan 1 1985

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Preparation and Reactivity of Mononuclear (η 5 -Cyclopentadienyl)cobalt Carbene Complexes . / Macomber, David W.; Rogers, Robin D.

In: Organometallics, Vol. 4, No. 8, 01.01.1985, p. 1485-1487.

Research output: Contribution to journalArticle

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N2 - (η 5 -C 5 H s )Co(CO) 2 reacts with bis(1,3-dimethylimidazolin-2-ylidene) to furnish the first mononuclear cyclopentadienylcobalt carbene complex 1. Complex 1 reacts with several electrophilic reagents including Ph 2 S 2 to produce the structurally characterized paramagnetic cyclopentadienylcobalt carbene complex 4.

AB - (η 5 -C 5 H s )Co(CO) 2 reacts with bis(1,3-dimethylimidazolin-2-ylidene) to furnish the first mononuclear cyclopentadienylcobalt carbene complex 1. Complex 1 reacts with several electrophilic reagents including Ph 2 S 2 to produce the structurally characterized paramagnetic cyclopentadienylcobalt carbene complex 4.

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