Preparation and Reactivity of Mononuclear (η5-Cyclopentadienyl)cobalt Carbene Complexes

David W. Macomber, Robin D. Rogers

Research output: Contribution to journalArticlepeer-review

45 Scopus citations

Abstract

5-C5Hs)Co(CO)2 reacts with bis(1,3-dimethylimidazolin-2-ylidene) to furnish the first mononuclear cyclopentadienylcobalt carbene complex 1. Complex 1 reacts with several electrophilic reagents including Ph2S2 to produce the structurally characterized paramagnetic cyclopentadienylcobalt carbene complex 4.

Original languageEnglish (US)
Pages (from-to)1485-1487
Number of pages3
JournalOrganometallics
Volume4
Issue number8
DOIs
StatePublished - Aug 1985

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