Preparation and chemistry of stable azidoiodinanes: 1-Azido-3,3-bis(trifluoromethyl)-3-(1H)-1,2-benziodoxol and 1-Azido-1,2-benziodoxol-3-(1H)-one

Viktor Zhdankin, Chris J. Kuehl, Alexei P. Krasutsky, Mark S. Formaneck, Jason T. Bolz

Research output: Contribution to journalArticle

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Abstract

Azidoiodinanes 2,4,6 can be prepared from benziodoxols 1,3 and trimethylsilyl azide in the form of stable, crystalline compounds. These compounds are potentially useful reagents for electrophilic azidonation of organic substrates. For example, reaction of azide 6 with cyclohexene affords 2-azidocyclohexanone 7 in moderate yield.

Original languageEnglish (US)
Pages (from-to)9677-9680
Number of pages4
JournalTetrahedron Letters
Volume35
Issue number52
DOIs
StatePublished - Dec 26 1994

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