TY - JOUR
T1 - Preparation and C-X reductive elimination reactivity of monoaryl Pd IV-X complexes in water (X = OH, OH2, Cl, Br)
AU - Oloo, Williamson
AU - Zavalij, Peter Y.
AU - Zhang, Jing
AU - Khaskin, Eugene
AU - Vedernikov, Andrei N.
PY - 2010/10/20
Y1 - 2010/10/20
N2 - Monohydrocarbyl palladium(IV) complexes bearing OH, OH2, Br, and Cl ligands at the metal and supported by facially chelating 1-hydroxy-1,1-bis(2-pyridyl)methoxide were readily prepared in water at 0 °C. These complexes reductively eliminate Ar-X (X = OH, Br, Cl) in water at room temperature in high yield, and the corresponding first-order rate constants kOH, kCl, and kBr are on the same order of magnitude.
AB - Monohydrocarbyl palladium(IV) complexes bearing OH, OH2, Br, and Cl ligands at the metal and supported by facially chelating 1-hydroxy-1,1-bis(2-pyridyl)methoxide were readily prepared in water at 0 °C. These complexes reductively eliminate Ar-X (X = OH, Br, Cl) in water at room temperature in high yield, and the corresponding first-order rate constants kOH, kCl, and kBr are on the same order of magnitude.
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U2 - 10.1021/ja107185w
DO - 10.1021/ja107185w
M3 - Article
C2 - 20866056
AN - SCOPUS:77958053622
VL - 132
SP - 14400
EP - 14402
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 41
ER -