Preparation and C-X reductive elimination reactivity of monoaryl Pd IV-X complexes in water (X = OH, OH2, Cl, Br)

Williamson Oloo, Peter Y. Zavalij, Jing Zhang, Eugene Khaskin, Andrei N. Vedernikov

Research output: Contribution to journalArticlepeer-review

64 Scopus citations

Abstract

Monohydrocarbyl palladium(IV) complexes bearing OH, OH2, Br, and Cl ligands at the metal and supported by facially chelating 1-hydroxy-1,1-bis(2-pyridyl)methoxide were readily prepared in water at 0 °C. These complexes reductively eliminate Ar-X (X = OH, Br, Cl) in water at room temperature in high yield, and the corresponding first-order rate constants kOH, kCl, and kBr are on the same order of magnitude.

Original languageEnglish (US)
Pages (from-to)14400-14402
Number of pages3
JournalJournal of the American Chemical Society
Volume132
Issue number41
DOIs
StatePublished - Oct 20 2010

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