Preparation and Bromination of a Sa.e-Dihydroindole1

Wayland E. Noland, Keun Jae Kim, Chang Kiu Lee, Sun Kun Bae, Chi Sun Hahn

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A 3a,6-dihydroindole was prepared by the Diels-Alder addition of dimethyl acetylenedicarboxylate to dimethyl [iV-(2,6-dimethylphenyl)pyrrol-2-yl]maleate. Subsequent reaction with bromine gave a 2,3-dibromoindoline which is different from that obtained from the corresponding 3a,7a-dihydroindole.

Original languageEnglish (US)
Pages (from-to)4582-4584
Number of pages3
JournalJournal of Organic Chemistry
Issue number23
StatePublished - Nov 1980

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