Abstract
We succeeded in preparing poly(ε-caprolactone) with hydroxyl chain end functionality by means of living ring-opening polymerization. The hydroxyl functionality at the chain end was successfully converted into anhydrous moiety via successive transformation reaction, i.e., carboxylation of hydroxyl group using maleic anhydride, introduction of conjugated diene under mitsunobu reaction, and Diels-Alder reaction of maleic anhydride and chain-end-diene group.
| Original language | English (US) |
|---|---|
| Title of host publication | Polymer Preprints, Japan - 55th SPSJ Annual Meeting |
| Number of pages | 1 |
| Volume | 55 |
| Edition | 1 |
| State | Published - Oct 18 2006 |
| Event | 55th SPSJ Annual Meeting - Nagoya, Japan Duration: May 24 2006 → May 26 2006 |
Other
| Other | 55th SPSJ Annual Meeting |
|---|---|
| Country | Japan |
| City | Nagoya |
| Period | 5/24/06 → 5/26/06 |
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Keywords
- Anhydride
- Diels-Alder reaction
- End-functionalized polymer
- Living polymerization
- Mitsunobu reaction
- Poly(ε-caprolactone)
Cite this
Precise synthesis of polymers functionalized with anhydride moieties. / Kakuchi, Ryohei; Shingo, Kobayashi; Sugiyama, Kenji; Hirao, Akira; Zhang, Jianbin; Hoye, Thomas R; Macosko, Chris.
Polymer Preprints, Japan - 55th SPSJ Annual Meeting. Vol. 55 1. ed. 2006.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
}
TY - GEN
T1 - Precise synthesis of polymers functionalized with anhydride moieties
AU - Kakuchi, Ryohei
AU - Shingo, Kobayashi
AU - Sugiyama, Kenji
AU - Hirao, Akira
AU - Zhang, Jianbin
AU - Hoye, Thomas R
AU - Macosko, Chris
PY - 2006/10/18
Y1 - 2006/10/18
N2 - We succeeded in preparing poly(ε-caprolactone) with hydroxyl chain end functionality by means of living ring-opening polymerization. The hydroxyl functionality at the chain end was successfully converted into anhydrous moiety via successive transformation reaction, i.e., carboxylation of hydroxyl group using maleic anhydride, introduction of conjugated diene under mitsunobu reaction, and Diels-Alder reaction of maleic anhydride and chain-end-diene group.
AB - We succeeded in preparing poly(ε-caprolactone) with hydroxyl chain end functionality by means of living ring-opening polymerization. The hydroxyl functionality at the chain end was successfully converted into anhydrous moiety via successive transformation reaction, i.e., carboxylation of hydroxyl group using maleic anhydride, introduction of conjugated diene under mitsunobu reaction, and Diels-Alder reaction of maleic anhydride and chain-end-diene group.
KW - Anhydride
KW - Diels-Alder reaction
KW - End-functionalized polymer
KW - Living polymerization
KW - Mitsunobu reaction
KW - Poly(ε-caprolactone)
UR - http://www.scopus.com/inward/record.url?scp=33749658235&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=33749658235&partnerID=8YFLogxK
M3 - Conference contribution
VL - 55
BT - Polymer Preprints, Japan - 55th SPSJ Annual Meeting
ER -