Polyacrylates with high biomass contents for pressure-sensitive adhesives prepared via mini-emulsion polymerization

Gang Pu; Matthew R. Dubay; Jiguang Zhang; Steven J. Severtson; Carl J. Houtman

doi:10.1021/ie301492v

Polyacrylates with high biomass contents for pressure-sensitive adhesives prepared via mini-emulsion polymerization

Gang Pu
, Matthew R. Dubay
, Jiguang Zhang
, Steven J. Severtson
, Carl J. Houtman

Bioproducts and Biosystems Engineering

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

n-Butyl acrylate and other acrylic monomers were copolymerized with an acrylated macromonomer to produce polymers for pressure-sensitive adhesive (PSA) applications. Macromonomers were generated through the ring-opening copolymerization of l-lactide and ε-caprolactone with 2-hydroxyethyl methacrylate (HEMA) at an average molar composition of 5:4:1, respectively. Conversion in the mini-emulsion polymerization was followed using Raman spectroscopy and was nearly complete within 2 h. Testing of these adhesive polymers indicates that performance properties meet or exceed those of commercial water-based acrylic PSAs.

Original language	English (US)
Pages (from-to)	12145-12149
Number of pages	5
Journal	Industrial and Engineering Chemistry Research
Volume	51
Issue number	37
DOIs	https://doi.org/10.1021/ie301492v
State	Published - Sep 19 2012

Publisher link

10.1021/ie301492v

Find It

Find It at U of M Libraries

Cite this

@article{83cb4fde46d746cf896516dc4009f070,

title = "Polyacrylates with high biomass contents for pressure-sensitive adhesives prepared via mini-emulsion polymerization",

abstract = "n-Butyl acrylate and other acrylic monomers were copolymerized with an acrylated macromonomer to produce polymers for pressure-sensitive adhesive (PSA) applications. Macromonomers were generated through the ring-opening copolymerization of l-lactide and ε-caprolactone with 2-hydroxyethyl methacrylate (HEMA) at an average molar composition of 5:4:1, respectively. Conversion in the mini-emulsion polymerization was followed using Raman spectroscopy and was nearly complete within 2 h. Testing of these adhesive polymers indicates that performance properties meet or exceed those of commercial water-based acrylic PSAs.",

author = "Gang Pu and Dubay, \{Matthew R.\} and Jiguang Zhang and Severtson, \{Steven J.\} and Houtman, \{Carl J.\}",

year = "2012",

month = sep,

day = "19",

doi = "10.1021/ie301492v",

language = "English (US)",

volume = "51",

pages = "12145--12149",

journal = "Industrial and Engineering Chemistry Research",

issn = "0888-5885",

publisher = "American Chemical Society",

number = "37",

}

TY - JOUR

T1 - Polyacrylates with high biomass contents for pressure-sensitive adhesives prepared via mini-emulsion polymerization

AU - Pu, Gang

AU - Dubay, Matthew R.

AU - Zhang, Jiguang

AU - Severtson, Steven J.

AU - Houtman, Carl J.

PY - 2012/9/19

Y1 - 2012/9/19

N2 - n-Butyl acrylate and other acrylic monomers were copolymerized with an acrylated macromonomer to produce polymers for pressure-sensitive adhesive (PSA) applications. Macromonomers were generated through the ring-opening copolymerization of l-lactide and ε-caprolactone with 2-hydroxyethyl methacrylate (HEMA) at an average molar composition of 5:4:1, respectively. Conversion in the mini-emulsion polymerization was followed using Raman spectroscopy and was nearly complete within 2 h. Testing of these adhesive polymers indicates that performance properties meet or exceed those of commercial water-based acrylic PSAs.

AB - n-Butyl acrylate and other acrylic monomers were copolymerized with an acrylated macromonomer to produce polymers for pressure-sensitive adhesive (PSA) applications. Macromonomers were generated through the ring-opening copolymerization of l-lactide and ε-caprolactone with 2-hydroxyethyl methacrylate (HEMA) at an average molar composition of 5:4:1, respectively. Conversion in the mini-emulsion polymerization was followed using Raman spectroscopy and was nearly complete within 2 h. Testing of these adhesive polymers indicates that performance properties meet or exceed those of commercial water-based acrylic PSAs.

UR - https://www.scopus.com/pages/publications/84866412631

UR - https://www.scopus.com/pages/publications/84866412631#tab=citedBy

U2 - 10.1021/ie301492v

DO - 10.1021/ie301492v

M3 - Article

AN - SCOPUS:84866412631

SN - 0888-5885

VL - 51

SP - 12145

EP - 12149

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 37

ER -

Polyacrylates with high biomass contents for pressure-sensitive adhesives prepared via mini-emulsion polymerization

Abstract

Publisher link

Find It

Other files and links

Fingerprint

Cite this