Poly(α-methyleneglutarimide)s from radical polymerization of α-methyleneglutarimides

Yuanxian Wang; Shu Xu; Thomas R. Hoye

doi:10.1002/pola.28977

Poly(α-methyleneglutarimide)s from radical polymerization of α-methyleneglutarimides

Yuanxian Wang, Shu Xu, Thomas R. Hoye

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Abstract

α-Methyleneglutaric acid, a metabolite of niacin (nicotinic acid), can be easily converted to its cyclic anhydride. We report here the first conversion of α-methyleneglutaric anhydride to (a series of) α-methyleneglutarimides. These monomers can be radically polymerized to the title polymers. These have relatively high glass transition properties compared to the lower homologs derived from itaconimides (α-methylenesuccinimides).

Original language	English (US)
Pages (from-to)	1020-1027
Number of pages	8
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	56
Issue number	9
DOIs	https://doi.org/10.1002/pola.28977
State	Published - May 1 2018

Bibliographical note

Publisher Copyright:
© 2018 Wiley Periodicals, Inc.

Keywords

AIBN-initiated radical polymerization
depolymerization
potential biosourced monomer evaluation
reversible addition-fragmentation chain-transfer (RAFT) polymerization
α-methyleneglutarate

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10.1002/pola.28977

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title = "Poly(α-methyleneglutarimide)s from radical polymerization of α-methyleneglutarimides",

abstract = "α-Methyleneglutaric acid, a metabolite of niacin (nicotinic acid), can be easily converted to its cyclic anhydride. We report here the first conversion of α-methyleneglutaric anhydride to (a series of) α-methyleneglutarimides. These monomers can be radically polymerized to the title polymers. These have relatively high glass transition properties compared to the lower homologs derived from itaconimides (α-methylenesuccinimides).",

keywords = "AIBN-initiated radical polymerization, depolymerization, potential biosourced monomer evaluation, reversible addition-fragmentation chain-transfer (RAFT) polymerization, α-methyleneglutarate",

author = "Yuanxian Wang and Shu Xu and Hoye, {Thomas R.}",

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T1 - Poly(α-methyleneglutarimide)s from radical polymerization of α-methyleneglutarimides

AU - Wang, Yuanxian

AU - Xu, Shu

AU - Hoye, Thomas R.

PY - 2018/5/1

Y1 - 2018/5/1

N2 - α-Methyleneglutaric acid, a metabolite of niacin (nicotinic acid), can be easily converted to its cyclic anhydride. We report here the first conversion of α-methyleneglutaric anhydride to (a series of) α-methyleneglutarimides. These monomers can be radically polymerized to the title polymers. These have relatively high glass transition properties compared to the lower homologs derived from itaconimides (α-methylenesuccinimides).

AB - α-Methyleneglutaric acid, a metabolite of niacin (nicotinic acid), can be easily converted to its cyclic anhydride. We report here the first conversion of α-methyleneglutaric anhydride to (a series of) α-methyleneglutarimides. These monomers can be radically polymerized to the title polymers. These have relatively high glass transition properties compared to the lower homologs derived from itaconimides (α-methylenesuccinimides).

KW - AIBN-initiated radical polymerization

KW - depolymerization

KW - potential biosourced monomer evaluation

KW - reversible addition-fragmentation chain-transfer (RAFT) polymerization

KW - α-methyleneglutarate

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JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

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ER -

Poly(α-methyleneglutarimide)s from radical polymerization of α-methyleneglutarimides

Abstract

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Keywords

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