Polarization selectivity in fifth-order electronically nonresonant Raman scattering from CS2

Laura J. Kaufman, David A. Blank, Graham R. Fleming

Research output: Contribution to journalArticlepeer-review

64 Scopus citations

Abstract

The tensor elements of the direct fifth-order Raman signal from CS2 were collected and analyzed. The collection of results reduce contamination from third-order cascade signals that are of varying importance in different tensor elements. As predicted, the different tensor elements weight particular Liouville pathways of the direct fifth-order signal undergoing molecular dynamics.

Original languageEnglish (US)
Pages (from-to)2312-2331
Number of pages20
JournalJournal of Chemical Physics
Volume114
Issue number5
DOIs
StatePublished - 2001

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