Plant Oil-Derived Epoxy Polymers toward Sustainable Biobased Thermosets

Zhongkai Wang; Liang Yuan; Mitra S. Ganewatta; Meghan E. Lamm; Md Anisur Rahman; Jifu Wang; Shengquan Liu; Chuanbing Tang

doi:10.1002/marc.201700009

Plant Oil-Derived Epoxy Polymers toward Sustainable Biobased Thermosets

Zhongkai Wang, Liang Yuan, Mitra S. Ganewatta, Meghan E. Lamm, Md Anisur Rahman, Jifu Wang, Shengquan Liu, Chuanbing Tang

Chemistry (Twin Cities)

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

Epoxy polymers (EPs) derived from soybean oil with varied chemical structures are synthesized. These polymers are then cured with anhydrides to yield soybean-oil-derived epoxy thermosets. The curing kinetic, thermal, and mechanical properties are well characterized. Due to the high epoxide functionality per epoxy polymer chain, these thermosets exhibit tensile strength over an order of magnitude higher than a control formulation with epoxidized soybean oil. More importantly, thermosetting materials ranging from soft elastomers to tough thermosets can be obtained simply by using different EPs and/or by controlling feed ratios of EPs to anhydrides. (Figure presented.).

Original language	English (US)
Article number	1700009
Journal	Macromolecular Rapid Communications
Volume	38
Issue number	11
DOIs	https://doi.org/10.1002/marc.201700009
State	Published - Jun 2017

Bibliographical note

Funding Information:
Support from the National Science Foundation (DMR-1252611) and National Science Foundation of China (51603002) are acknowledged.

Publisher Copyright:
© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Keywords

biobased
epoxy
soybean oil
thermoset

Publisher link

10.1002/marc.201700009

Find It

Find It at U of M Libraries

Cite this

@article{baecb43c87d2481c97046bafc555cbfe,

title = "Plant Oil-Derived Epoxy Polymers toward Sustainable Biobased Thermosets",

abstract = "Epoxy polymers (EPs) derived from soybean oil with varied chemical structures are synthesized. These polymers are then cured with anhydrides to yield soybean-oil-derived epoxy thermosets. The curing kinetic, thermal, and mechanical properties are well characterized. Due to the high epoxide functionality per epoxy polymer chain, these thermosets exhibit tensile strength over an order of magnitude higher than a control formulation with epoxidized soybean oil. More importantly, thermosetting materials ranging from soft elastomers to tough thermosets can be obtained simply by using different EPs and/or by controlling feed ratios of EPs to anhydrides. (Figure presented.).",

keywords = "biobased, epoxy, soybean oil, thermoset",

author = "Zhongkai Wang and Liang Yuan and Ganewatta, {Mitra S.} and Lamm, {Meghan E.} and Rahman, {Md Anisur} and Jifu Wang and Shengquan Liu and Chuanbing Tang",

note = "Funding Information: Support from the National Science Foundation (DMR-1252611) and National Science Foundation of China (51603002) are acknowledged. Publisher Copyright: {\textcopyright} 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2017",

month = jun,

doi = "10.1002/marc.201700009",

language = "English (US)",

volume = "38",

journal = "Macromolecular Rapid Communications",

issn = "1022-1336",

publisher = "Wiley-VCH Verlag",

number = "11",

}

TY - JOUR

T1 - Plant Oil-Derived Epoxy Polymers toward Sustainable Biobased Thermosets

AU - Wang, Zhongkai

AU - Yuan, Liang

AU - Ganewatta, Mitra S.

AU - Lamm, Meghan E.

AU - Rahman, Md Anisur

AU - Wang, Jifu

AU - Liu, Shengquan

AU - Tang, Chuanbing

N1 - Funding Information: Support from the National Science Foundation (DMR-1252611) and National Science Foundation of China (51603002) are acknowledged. Publisher Copyright: © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

PY - 2017/6

Y1 - 2017/6

N2 - Epoxy polymers (EPs) derived from soybean oil with varied chemical structures are synthesized. These polymers are then cured with anhydrides to yield soybean-oil-derived epoxy thermosets. The curing kinetic, thermal, and mechanical properties are well characterized. Due to the high epoxide functionality per epoxy polymer chain, these thermosets exhibit tensile strength over an order of magnitude higher than a control formulation with epoxidized soybean oil. More importantly, thermosetting materials ranging from soft elastomers to tough thermosets can be obtained simply by using different EPs and/or by controlling feed ratios of EPs to anhydrides. (Figure presented.).

AB - Epoxy polymers (EPs) derived from soybean oil with varied chemical structures are synthesized. These polymers are then cured with anhydrides to yield soybean-oil-derived epoxy thermosets. The curing kinetic, thermal, and mechanical properties are well characterized. Due to the high epoxide functionality per epoxy polymer chain, these thermosets exhibit tensile strength over an order of magnitude higher than a control formulation with epoxidized soybean oil. More importantly, thermosetting materials ranging from soft elastomers to tough thermosets can be obtained simply by using different EPs and/or by controlling feed ratios of EPs to anhydrides. (Figure presented.).

KW - biobased

KW - epoxy

KW - soybean oil

KW - thermoset

UR - http://www.scopus.com/inward/record.url?scp=85017209812&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85017209812&partnerID=8YFLogxK

U2 - 10.1002/marc.201700009

DO - 10.1002/marc.201700009

M3 - Article

C2 - 28321946

AN - SCOPUS:85017209812

SN - 1022-1336

VL - 38

JO - Macromolecular Rapid Communications

JF - Macromolecular Rapid Communications

IS - 11

M1 - 1700009

ER -

Plant Oil-Derived Epoxy Polymers toward Sustainable Biobased Thermosets

Abstract

Bibliographical note

Keywords

Publisher link

Find It

Other files and links

Fingerprint

Cite this