Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst

Limin Ren; Qiang Guo; Marat Orazov; Dandan Xu; Dorothea Politi; Prashant Kumar; Saeed M. Alhassan; K. Andre Mkhoyan; Dimitrios Sidiras; Mark E. Davis; Michael Tsapatsis

doi:10.1002/cctc.201600120

Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst

Limin Ren, Qiang Guo, Marat Orazov, Dandan Xu, Dorothea Politi, Prashant Kumar, Saeed M. Alhassan, K. Andre Mkhoyan, Dimitrios Sidiras, Mark E. Davis, Michael Tsapatsis

Chemical Engineering and Materials Science

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

Pillared Sn-MWW (Sn-MWW(SP)-SSE) was prepared through a solid-state-exchange (SSE) route. The pillared structure was inherited from pillared B-MWW, and Sn was inserted in the framework by boron leaching and solid-state-exchange with tin tetrachloride pentahydrate. The Sn-MWW(SP)-SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer-Villiger oxidation, and mono- and disaccharide isomerizations.

Original language	English (US)
Pages (from-to)	1274-1278
Number of pages	5
Journal	ChemCatChem
Volume	8
Issue number	7
DOIs	https://doi.org/10.1002/cctc.201600120
State	Published - Apr 6 2016

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Publisher Copyright:
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Keywords

Lewis acids
isomerization
layered materials
solid-state-exchange
zeolites

Publisher link

10.1002/cctc.201600120

https://authors.library.caltech.edu/67040/1/cctc201600120-sup-0001-misc_information.pdf

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title = "Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst",

abstract = "Pillared Sn-MWW (Sn-MWW(SP)-SSE) was prepared through a solid-state-exchange (SSE) route. The pillared structure was inherited from pillared B-MWW, and Sn was inserted in the framework by boron leaching and solid-state-exchange with tin tetrachloride pentahydrate. The Sn-MWW(SP)-SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer-Villiger oxidation, and mono- and disaccharide isomerizations.",

keywords = "Lewis acids, isomerization, layered materials, solid-state-exchange, zeolites",

author = "Limin Ren and Qiang Guo and Marat Orazov and Dandan Xu and Dorothea Politi and Prashant Kumar and Alhassan, \{Saeed M.\} and Mkhoyan, \{K. Andre\} and Dimitrios Sidiras and Davis, \{Mark E.\} and Michael Tsapatsis",

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doi = "10.1002/cctc.201600120",

language = "English (US)",

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AU - Ren, Limin

AU - Guo, Qiang

AU - Orazov, Marat

AU - Xu, Dandan

AU - Politi, Dorothea

AU - Kumar, Prashant

AU - Alhassan, Saeed M.

AU - Mkhoyan, K. Andre

AU - Sidiras, Dimitrios

AU - Davis, Mark E.

AU - Tsapatsis, Michael

PY - 2016/4/6

Y1 - 2016/4/6

N2 - Pillared Sn-MWW (Sn-MWW(SP)-SSE) was prepared through a solid-state-exchange (SSE) route. The pillared structure was inherited from pillared B-MWW, and Sn was inserted in the framework by boron leaching and solid-state-exchange with tin tetrachloride pentahydrate. The Sn-MWW(SP)-SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer-Villiger oxidation, and mono- and disaccharide isomerizations.

AB - Pillared Sn-MWW (Sn-MWW(SP)-SSE) was prepared through a solid-state-exchange (SSE) route. The pillared structure was inherited from pillared B-MWW, and Sn was inserted in the framework by boron leaching and solid-state-exchange with tin tetrachloride pentahydrate. The Sn-MWW(SP)-SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer-Villiger oxidation, and mono- and disaccharide isomerizations.

KW - Lewis acids

KW - isomerization

KW - layered materials

KW - solid-state-exchange

KW - zeolites

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DO - 10.1002/cctc.201600120

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VL - 8

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JO - ChemCatChem

JF - ChemCatChem

IS - 7

ER -

Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst

Abstract

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