Photoluminescence Properties of Eu-Doped MIL-53(Fe) Obtained by Solvothermal Synthesis

Vinh H Nguyen; Long Giang Bach; Sy Trung Do; Nguyen Thi Thuong; Trinh Duy Nguyen

doi:10.1166/jnn.2019.15922

Photoluminescence Properties of Eu-Doped MIL-53(Fe) Obtained by Solvothermal Synthesis

Vinh H Nguyen
, Long Giang Bach
, Sy Trung Do
, Nguyen Thi Thuong
, Trinh Duy Nguyen

Anesthesiology

Research output: Contribution to journal › Article › peer-review

Abstract

We report the facial synthesis of Eu-doped MIL-53(Fe) elongated hexagonal dipyramid by solvothermal reaction of Fe(NO₃)₃, Eu(NO₃)₃ and terephthalic acid (TPA) in the presence of N,N-dimethylformamide (DMF). The as-synthesized samples were characterized by XRD, Raman, FT-IR, PL, and SEM. From XRD and Raman results, metal replacement (Eu) with the metal ion (Fe) in the crystal lattice may change the high crystallinity of the MIL-53(Fe) structure, and all the metal ions were incorporated into the structures of MIL-53(Fe) as well as replaced Fe ion or located at interstitial site. From PL result, Eu-doped MIL-53(Fe) showed unique Eu fluorescence properties with high emission intensity, thus enabling it to be a promising functional probe for fluorescent imaging.

Original language	English (US)
Pages (from-to)	1148-1150
Number of pages	3
Journal	Journal of Nanoscience and Nanotechnology
Volume	19
Issue number	2
DOIs	https://doi.org/10.1166/jnn.2019.15922
State	Published - Feb 1 2019

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title = "Photoluminescence Properties of Eu-Doped MIL-53(Fe) Obtained by Solvothermal Synthesis",

abstract = "We report the facial synthesis of Eu-doped MIL-53(Fe) elongated hexagonal dipyramid by solvothermal reaction of Fe(NO₃)₃, Eu(NO₃)₃ and terephthalic acid (TPA) in the presence of N,N-dimethylformamide (DMF). The as-synthesized samples were characterized by XRD, Raman, FT-IR, PL, and SEM. From XRD and Raman results, metal replacement (Eu) with the metal ion (Fe) in the crystal lattice may change the high crystallinity of the MIL-53(Fe) structure, and all the metal ions were incorporated into the structures of MIL-53(Fe) as well as replaced Fe ion or located at interstitial site. From PL result, Eu-doped MIL-53(Fe) showed unique Eu fluorescence properties with high emission intensity, thus enabling it to be a promising functional probe for fluorescent imaging.",

author = "Nguyen, \{Vinh H\} and Bach, \{Long Giang\} and Do, \{Sy Trung\} and Thuong, \{Nguyen Thi\} and Nguyen, \{Trinh Duy\}",

year = "2019",

month = feb,

day = "1",

doi = "10.1166/jnn.2019.15922",

language = "English (US)",

volume = "19",

pages = "1148--1150",

journal = "Journal of Nanoscience and Nanotechnology",

issn = "1533-4880",

publisher = "American Scientific Publishers",

number = "2",

}

TY - JOUR

T1 - Photoluminescence Properties of Eu-Doped MIL-53(Fe) Obtained by Solvothermal Synthesis

AU - Nguyen, Vinh H

AU - Bach, Long Giang

AU - Do, Sy Trung

AU - Thuong, Nguyen Thi

AU - Nguyen, Trinh Duy

PY - 2019/2/1

Y1 - 2019/2/1

N2 - We report the facial synthesis of Eu-doped MIL-53(Fe) elongated hexagonal dipyramid by solvothermal reaction of Fe(NO₃)₃, Eu(NO₃)₃ and terephthalic acid (TPA) in the presence of N,N-dimethylformamide (DMF). The as-synthesized samples were characterized by XRD, Raman, FT-IR, PL, and SEM. From XRD and Raman results, metal replacement (Eu) with the metal ion (Fe) in the crystal lattice may change the high crystallinity of the MIL-53(Fe) structure, and all the metal ions were incorporated into the structures of MIL-53(Fe) as well as replaced Fe ion or located at interstitial site. From PL result, Eu-doped MIL-53(Fe) showed unique Eu fluorescence properties with high emission intensity, thus enabling it to be a promising functional probe for fluorescent imaging.

AB - We report the facial synthesis of Eu-doped MIL-53(Fe) elongated hexagonal dipyramid by solvothermal reaction of Fe(NO₃)₃, Eu(NO₃)₃ and terephthalic acid (TPA) in the presence of N,N-dimethylformamide (DMF). The as-synthesized samples were characterized by XRD, Raman, FT-IR, PL, and SEM. From XRD and Raman results, metal replacement (Eu) with the metal ion (Fe) in the crystal lattice may change the high crystallinity of the MIL-53(Fe) structure, and all the metal ions were incorporated into the structures of MIL-53(Fe) as well as replaced Fe ion or located at interstitial site. From PL result, Eu-doped MIL-53(Fe) showed unique Eu fluorescence properties with high emission intensity, thus enabling it to be a promising functional probe for fluorescent imaging.

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U2 - 10.1166/jnn.2019.15922

DO - 10.1166/jnn.2019.15922

M3 - Article

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SN - 1533-4880

VL - 19

SP - 1148

EP - 1150

JO - Journal of Nanoscience and Nanotechnology

JF - Journal of Nanoscience and Nanotechnology

IS - 2

ER -

Photoluminescence Properties of Eu-Doped MIL-53(Fe) Obtained by Solvothermal Synthesis

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